journal article·2025-11-11

Pechini Method Revisited: From Synthesis Innovation to Multifunctional Materials

Zhixin Yao, U. Sasaki, Xuanyu Zhang, Lei Liu

Chemistry of Materials· Volume 37· Issue 21
Publisher page

Abstract

Overcoming the single-function limitation of the conventional solution synthesis, we present the approach of Pechini 2.0 – a fluidic platform leveraging dynamic wet-gel states for the design of multifunctional material. This perspective delineates a transition from the conventional crystal and/or powder production (Pechini 1.0) to engineered amorphous integration as exemplified by the following two aspects: (i) core–shell encapsulation to engage mutually exclusive properties ( e.g ., thermal conductor vs electrical insulator), and (ii) transferable amorphous metal oxide films realizing damage-free van der Waals integration to two-dimensional electronics. By treating amorphous phases as functional end-products rather than transient intermediates, this framework accesses spaces inaccessible to crystalline systems. We further conceptualize Pechini 2.0 as a material innovation tree, projecting three critical trajectories, including uncovering structure–property relationships in noncrystalline oxides, expanding composition spaces toward multianion systems, and bridging lab-scale synthesis with scalable manufacturing. This positions Pechini 2.0 as one key foundation to next-generation material paradigms.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · TiO2 Photocatalysis and Solar Cells · Dielectric properties of ceramics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering

Peking University

Interdisciplinary Institute of Light-Element Quantum Materials and Research Center for Light-Element Advanced Materials

Funding

National Key Research and Development Program of China · Natural Science Foundation of Beijing Municipality · National Natural Science Foundation of China

References (67)

Show source-provided references
1. 10.1002/adfm.20190463210.1002/adfm.201904632 ↗
2. 10.1155/2021/510201410.1155/2021/5102014 ↗
3. 10.1016/j.pmatsci.2015.12.00110.1016/j.pmatsci.2015.12.001 ↗
4. 10.1039/C5MH00260E10.1039/C5MH00260E ↗
5. Pechini, M. P. Method of Preparing Lead and Alkaline Earth Titanates and Niobates and Coating Method Using the Same to Form a Capacitor. US3330697A, 1967.
6. 10.1246/bcsj.72.142710.1246/bcsj.72.1427 ↗
7. Sunde T. O. L. · 2016 · 1
8. Dimesso L. · 2016 · 1
9. 10.1021/jp070062c10.1021/jp070062c ↗
10. 10.1016/j.matdes.2024.11311810.1016/j.matdes.2024.113118 ↗
11. 10.1007/s10971-015-3837-710.1007/s10971-015-3837-7 ↗
12. 10.1557/mrs2000.17610.1557/mrs2000.176 ↗
13. 10.1016/j.powtec.2015.03.04910.1016/j.powtec.2015.03.049 ↗
14. 10.1016/j.jeurceramsoc.2006.05.00210.1016/j.jeurceramsoc.2006.05.002 ↗
15. 10.1002/pssa.20100076010.1002/pssa.201000760 ↗
16. 10.1016/j.materresbull.2012.09.04310.1016/j.materresbull.2012.09.043 ↗
17. 10.1016/j.molliq.2016.06.06710.1016/j.molliq.2016.06.067 ↗
18. 10.1023/A:102264932494410.1023/A:1022649324944 ↗
19. 10.1021/acsnano.4c0934610.1021/acsnano.4c09346 ↗
20. 10.1038/s41467-025-56815-910.1038/s41467-025-56815-9 ↗
21. 10.1021/acs.nanolett.1c0459810.1021/acs.nanolett.1c04598 ↗
22. 10.1038/natrevmats.2016.4210.1038/natrevmats.2016.42 ↗
23. 10.1038/s41586-022-05617-w10.1038/s41586-022-05617-w ↗
24. 10.1021/acsnano.3c0959310.1021/acsnano.3c09593 ↗
25. 10.1039/D4RA01523A10.1039/D4RA01523A ↗
26. 10.1038/s44160-024-00657-810.1038/s44160-024-00657-8 ↗
27. 10.1038/s41586-020-2375-910.1038/s41586-020-2375-9 ↗
28. 10.1002/smll.20180437110.1002/smll.201804371 ↗
29. 10.1088/0256-307X/42/6/06610110.1088/0256-307X/42/6/066101 ↗
30. 10.1002/adfm.20242475110.1002/adfm.202424751 ↗
31. 10.1016/j.coco.2020.10043010.1016/j.coco.2020.100430 ↗
32. 10.1002/adma.20220102310.1002/adma.202201023 ↗
33. 10.1002/admi.20220219610.1002/admi.202202196 ↗
34. 10.1016/j.jallcom.2022.16712310.1016/j.jallcom.2022.167123 ↗
35. 10.1016/j.mseb.2017.12.02910.1016/j.mseb.2017.12.029 ↗
36. 10.1063/1.212338210.1063/1.2123382 ↗
37. 10.1016/j.jcis.2021.07.07410.1016/j.jcis.2021.07.074 ↗
38. 10.4028/www.scientific.net/AMR.1098.9210.4028/www.scientific.net/AMR.1098.92 ↗
39. 10.1039/c1nr11000d10.1039/c1nr11000d ↗
40. 10.1016/j.progsolidstchem.2013.09.00110.1016/j.progsolidstchem.2013.09.001 ↗
41. 10.1038/s41586-022-04588-210.1038/s41586-022-04588-2 ↗
42. 10.1038/s41565-022-01221-110.1038/s41565-022-01221-1 ↗
43. 10.1038/s41928-022-00877-w10.1038/s41928-022-00877-w ↗
44. 10.1038/s41928-022-00753-710.1038/s41928-022-00753-7 ↗
45. 10.1038/s41467-023-37887-x10.1038/s41467-023-37887-x ↗
46. 10.1038/s41467-024-53907-w10.1038/s41467-024-53907-w ↗
47. 10.1038/s41586-024-07786-210.1038/s41586-024-07786-2 ↗
48. 10.1007/s40820-016-0089-110.1007/s40820-016-0089-1 ↗
49. 10.1016/j.pcrysgrow.2014.04.00110.1016/j.pcrysgrow.2014.04.001 ↗
50. 10.1007/s12034-008-0010-810.1007/s12034-008-0010-8 ↗
51. 10.1002/aelm.20190032210.1002/aelm.201900322 ↗
52. 10.1021/acs.chemmater.7b0134610.1021/acs.chemmater.7b01346 ↗
53. 10.1111/jace.1202010.1111/jace.12020 ↗
54. 10.1063/1.325939210.1063/1.3259392 ↗
55. 10.1016/j.jeurceramsoc.2012.05.00710.1016/j.jeurceramsoc.2012.05.007 ↗
56. 10.1016/j.jeurceramsoc.2004.02.02110.1016/j.jeurceramsoc.2004.02.021 ↗
57. 10.1021/cm071827w10.1021/cm071827w ↗
58. 10.1111/j.1551-2916.2006.01062.x10.1111/j.1551-2916.2006.01062.x ↗
59. 10.1016/j.matlet.2011.09.08110.1016/j.matlet.2011.09.081 ↗
60. 10.1021/acsaelm.0c0027710.1021/acsaelm.0c00277 ↗
61. 10.1016/j.tsf.2011.06.10710.1016/j.tsf.2011.06.107 ↗
62. 10.1016/j.solener.2016.08.04510.1016/j.solener.2016.08.045 ↗
63. 10.1021/acs.jpclett.5c0125910.1021/acs.jpclett.5c01259 ↗
64. 10.1103/PhysRevLett.129.10760110.1103/PhysRevLett.129.107601 ↗
65. 10.1038/s41467-024-47688-510.1038/s41467-024-47688-5 ↗
66. 10.1038/s41467-021-22356-010.1038/s41467-021-22356-0 ↗
67. 10.1126/sciadv.aav435510.1126/sciadv.aav4355 ↗