journal article·2024-06-11

Are Barium Ruthenates Interesting?

R.J. Cava, Weiwei Xie

Chemistry of Materials· Volume 36· Issue 11
Publisher page

Abstract

We argue that there are at least three characteristics that make barium ruthenium oxides interesting. The first of these is the multifaceted formal valence of the Ru ions present, second is the Ru–O hybridization, which leads to “fractional” Ru oxidation states in some cases and the widespread existence of low resistivity metallic conductors among ruthenates, and third is the peculiar two-dimensional geometry (which includes pentagons) of some of the Ba–O layers present.
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Research context

OpenAlex topics: Advanced Condensed Matter Physics · Rare-earth and actinide compounds · Magnetic and transport properties of perovskites and related materials

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Affiliations

Department of Chemistry Frick Chemical Laboratory, Princeton University, Washington Road, Room A88, Princeton, New Jersey 08544, United States

Department of Chemistry, Michigan State University, 578 S Shore Lane Room 311, East Lansing, Michigan 48824, United States

Funding

Basic Energy Sciences

References (14)

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