Au-Acyclic Diaminocarbene-Linked Homochiral Covalent Organic Frameworks: Synthesis and Asymmetric Catalytic Application
Source abstract
Abstract
Chiral covalent organic framework (CCOF)-based heterogeneous catalysts are the new hot topic in asymmetric catalysis. The chiral metal-acyclic diaminocarbene complexes (M-ADCs), on the other hand, make up a powerful class of homogeneous catalysts for various asymmetric organic transformations. The integration of chiral M-ADCs with COFs into a single platform will undoubtedly lead to a new breed of heterogeneous asymmetric catalysts. Here, we report the synthesis of Au-ADC-linked CCOFs via a metal-mediated nucleophilic addition approach. This research not only provides a new type of COF linkage but also affords a new kind of heterogeneous catalysts for asymmetric catalysis.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education
Shandong Normal University
Funding
Taishan Scholar Project of Shandong Province · National Natural Science Foundation of China · Natural Science Foundation of Shandong Province · Project of Shandong Province Higher Educational Science and Technology Program
References (20)
Show source-provided references
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