journal article·2023-11-14

Interplanar Magnetic Orders and Symmetry-Tuned Zero Thermal Expansion in Kagomé Metal (Zr,Ta)Fe2

Yili Cao, Yong Xu, Sergii Khmelevskyi, Maxim Avdeev, Chin-Wei Wang, Shixin Hu, Koji Ohara, Yuanhua Xia, Xin Chen, Qiang Li, Jinxia Deng, Jun Miao, Kun Lin, Xianran Xing

Chemistry of Materials· Volume 35· Issue 21
Publisher page

Abstract

An alternative strategy was proposed for a family of kagomé metals (Zr,Ta)Fe 2 to tailor thermal expansion by utilizing thermodynamic phase stability rather than by conventionally altering chemical composition. An isotropic zero thermal expansion (ZTE, α l ∼ + 0.9 × 10 –6 K –1, 10–430 K) is demonstrated in high-quality cubic ingots over a superior magnetic ordering temperature window up to 430 K. A combined neutron diffraction, Mössbauer spectrum, and theoretical calculations analysis fundamentally uncover that the magnetic ordering of adjacent kagomé Fe-layers intimately changes from antiferromagnetic to ferromagnetic on transforming from hexagonal to cubic symmetry. Due to lifting of the interplanar magnetic frustration, magnetic ordering is enhanced and enables a strong temperature-induced longitudinal spin fluctuations, thus leading to large magnetic compensation for lattice thermal expansion.
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Research context

OpenAlex topics: Thermal Expansion and Ionic Conductivity · Advanced Condensed Matter Physics · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China

Research Center for Computational Materials Science and Engineering, Vienna University of Technology, Karlplatz 13, A-1040 Vienna, Austria

Australian Nuclear Science and Technology Organisation, Lucas Heights, New South Wales 2234, Australia

School of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia

Neutron Group, National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan

Institute of Applied Magnetics, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China

Faculty of Materials for Energy, Shimane University, 1060, Nishikawatsu-cho, Matsue, Shimane 690-8504, Japan

Institutes of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621999, China

Funding

National Key Research and Development Program of China · National Natural Science Foundation of China

References (55)

Show source-provided references
1. 10.1103/RevModPhys.90.01500110.1103/RevModPhys.90.015001 ↗
2. 10.1038/nature2616010.1038/nature26160 ↗
3. 10.1038/s42254-019-0038-210.1038/s42254-019-0038-2 ↗
4. 10.1126/science.aaw166610.1126/science.aaw1666 ↗
5. 10.1038/s41563-019-0589-810.1038/s41563-019-0589-8 ↗
6. 10.1103/PhysRevLett.126.24660210.1103/PhysRevLett.126.246602 ↗
7. 10.1126/sciadv.abe268010.1126/sciadv.abe2680 ↗
8. 10.1038/s41563-019-0531-010.1038/s41563-019-0531-0 ↗
9. 10.1038/nature2598710.1038/nature25987 ↗
10. 10.1038/s41567-018-0234-510.1038/s41567-018-0234-5 ↗
11. 10.1002/adma.20220135010.1002/adma.202201350 ↗
12. 10.1038/s41567-021-01404-y10.1038/s41567-021-01404-y ↗
13. 10.1126/science.115144210.1126/science.1151442 ↗
14. 10.1021/acs.chemrev.1c0075610.1021/acs.chemrev.1c00756 ↗
15. 10.1021/acs.chemmater.1c0100710.1021/acs.chemmater.1c01007 ↗
16. 10.1039/C8MH01065J10.1039/C8MH01065J ↗
17. 10.1063/1.490825810.1063/1.4908258 ↗
18. 10.1063/1.311004610.1063/1.3110046 ↗
19. 10.1016/j.scriptamat.2020.04.04310.1016/j.scriptamat.2020.04.043 ↗
20. 10.1002/adma.20160181610.1002/adma.201601816 ↗
21. 10.1002/adma.20160031010.1002/adma.201600310 ↗
22. 10.1021/ja044959o10.1021/ja044959o ↗
23. 10.1016/j.actamat.2022.11835010.1016/j.actamat.2022.118350 ↗
24. 10.1073/pnas.202318111810.1073/pnas.2023181118 ↗
25. 10.1016/j.matpr.2020.12.52710.1016/j.matpr.2020.12.527 ↗
26. 10.1038/nature0201110.1038/nature02011 ↗
27. 10.1021/acsami.0c1841610.1021/acsami.0c18416 ↗
28. 10.1021/am403227c10.1021/am403227c ↗
29. 10.1016/j.scriptamat.2014.04.01010.1016/j.scriptamat.2014.04.010 ↗
30. 10.1002/adma.20110255210.1002/adma.201102552 ↗
31. 10.1002/adma.20220863510.1002/adma.202208635 ↗
32. 10.1021/acs.inorgchem.9b0048010.1021/acs.inorgchem.9b00480 ↗
33. 10.1021/acs.chemmater.5b0042910.1021/acs.chemmater.5b00429 ↗
34. 10.1002/adfm.20160419510.1002/adfm.201604195 ↗
35. 10.1103/PhysRevLett.127.05550110.1103/PhysRevLett.127.055501 ↗
36. 10.1007/s40843-021-1996-210.1007/s40843-021-1996-2 ↗
37. 10.1016/j.matpr.2020.12.52710.1016/j.matpr.2020.12.527 ↗
38. 10.1016/0304-8853(91)90828-X10.1016/0304-8853(91)90828-X ↗
39. 10.1103/PhysRevLett.107.06590110.1103/PhysRevLett.107.065901 ↗
40. 10.1103/PhysRevB.47.1653210.1103/PhysRevB.47.16532 ↗
41. 10.1016/S0927-0256(99)00003-810.1016/S0927-0256(99)00003-8 ↗
42. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗
43. 10.1088/0305-4608/15/6/01810.1088/0305-4608/15/6/018 ↗
44. 10.1002/pssa.221078024110.1002/pssa.2210780241 ↗
45. 10.1002/adma.20210959210.1002/adma.202109592 ↗
46. 10.1103/PhysRev.135.A15110.1103/PhysRev.135.A151 ↗
47. 10.1103/PhysRevB.7.422010.1103/PhysRevB.7.4220 ↗
48. 10.1038/s41467-021-25036-110.1038/s41467-021-25036-1 ↗
49. 10.1088/0305-4608/15/6/01810.1088/0305-4608/15/6/018 ↗
50. 10.1016/0304-8853(87)90721-910.1016/0304-8853(87)90721-9 ↗
51. 10.1103/PhysRevB.67.21430210.1103/PhysRevB.67.214302 ↗
52. 10.1103/PhysRevB.82.13440210.1103/PhysRevB.82.134402 ↗
53. 10.1103/PhysRevB.75.05440210.1103/PhysRevB.75.054402 ↗
54. 10.1103/PhysRevB.87.01440510.1103/PhysRevB.87.014405 ↗
55. 10.1016/j.jmmm.2018.04.02310.1016/j.jmmm.2018.04.023 ↗