journal article·2025-01-14Open access

Oriented and Area-Selective Growth of Zeolitic Imidazolate Framework-8 Films by Molecular Layer Deposition

Jorid Smets, Víctor Rubio-Giménez, Jesús Gándara-Loe, Jonas Adriaenssens, Mario Fratschko, Fabian Gasser, Roland Resel, Anita Brady-Boyd, Rajeshreddy Ninakanti, Steven De Feyter, Silvia Armini, Rob Ameloot

Chemistry of Materials· Volume 37· Issue 1

Abstract

Integrating metal–organic frameworks (MOFs) into microfabrication processes will benefit from controlled vapor-phase deposition techniques. This study presents a molecular layer deposition method that enables area-selective and oriented growth of zeolitic imidazolate framework-8 (ZIF-8) films. Substrates functionalized with self-assembled monolayers (SAMs) with different end groups (alkyl, phenyl, hydroxyl, carboxyl, amine, and imidazole) allow tuning the degree of crystallographic orientation in the resulting MOF layers. Spatial control over SAM formation determined the surface mobility of the ZIF-8 building blocks, which enabled area-selective deposition.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Semiconductor materials and devices · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven − University of Leuven, Celestijnenlaan 200F, Leuven 3001, Belgium

Imec, Kapeldreef 75, Leuven 3001, Belgium

Antwerp Engineering, Photoelectrochemistry and Sensing (A-PECS), Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, Antwerp 2020, Belgium

Institute of Solid State Physics, Graz University of Technology, Petersgasse 16, Graz 8010, Austria

Electron Microscopy for Material Science (EMAT) and NANOlab Center of Excellence, Department of Physics, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium

Department of Chemistry, Division of Molecular Imaging and Photonics, KU Leuven, Leuven 3001, Belgium

Funding

Agentschap Innoveren en Ondernemen · KU Leuven · H2020 Marie Sklodowska-Curie Actions · Fonds Wetenschappelijk Onderzoek · Fonds De La Recherche Scientifique - FNRS · H2020 European Research Council

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