Room-Temperature Bistability in Spin Crossover-Loaded Metal–Organic Frameworks
Source abstract
Abstract
In this article, we present an unprecedented strategy to prepare bistable porous nanocrystals based on the anchoring of switchable molecules in the pores of a host matrix through strong host–guest interactions. More precisely, we have inserted a prototypical Fe(III) spin-crossover complex in MOF-808, a chemically robust large-pore Zr-based MOF. The loaded nanocrystals present a hysteretic thermal spin transition close to room temperature that is independent of the complex loading and the MOF particle size while remaining highly porous, which opens up opportunities for their use as chemical sensors.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Magnetism in coordination complexes · Metal-Organic Frameworks: Synthesis and Applications · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL University, 75005 Paris, France
Institut des Molécules et Matériaux du Mans-IMMM-UMR CNRS 6283, Le Mans Université, 72085 Le Mans Cedex 9, France
Centre de Nanosciences et de Nanotechnologies, Université Paris-Saclay, CNRS, 91120 Palaiseau, France
Department of Physical Chemistry, University of Geneva, 1211 Geneva, Switzerland
Funding
Agence Nationale de la Recherche · H2020 Marie Sklodowska-Curie Actions
References (43)
Show source-provided references
1. 10.1002/anie.20190066610.1002/anie.201900666 ↗
2. 10.1039/C9CS00778D10.1039/C9CS00778D ↗
3. 10.3762/bjoc.9.3910.3762/bjoc.9.39 ↗
4. Spiering, H. Elastic Interaction in Spin Crossover Compounds, 2004; p 171.10.1007/b95427 ↗
5. 10.1002/andp.20190007610.1002/andp.201900076 ↗
6. 10.1039/c1cs15046d10.1039/c1cs15046d ↗
7. 10.1002/anie.20080603910.1002/anie.200806039 ↗
8. 10.1016/j.ccr.2016.12.00210.1016/j.ccr.2016.12.002 ↗
9. 10.1002/ejic.20200055310.1002/ejic.202000553 ↗
10. 10.1021/ic800803w10.1021/ic800803w ↗
11. 10.1002/adma.20170386210.1002/adma.201703862 ↗
12. 10.1039/c1cc14463d10.1039/c1cc14463d ↗
13. 10.1039/c2jm33865c10.1039/c2jm33865c ↗
14. 10.1063/1.495926210.1063/1.4959262 ↗
15. 10.1039/C8CP00775F10.1039/C8CP00775F ↗
16. 10.1039/c3994000089310.1039/c39940000893 ↗
17. 10.1039/A707887K10.1039/A707887K ↗
18. 10.1039/C6CC03667H10.1039/C6CC03667H ↗
19. 10.1039/C6TC01297C10.1039/C6TC01297C ↗
20. 10.1039/C7CS00653E10.1039/C7CS00653E ↗
21. 10.1126/science.123044410.1126/science.1230444 ↗
22. 10.1039/C8CC07573E10.1039/C8CC07573E ↗
23. 10.1039/D0TC03756G10.1039/D0TC03756G ↗
24. 10.1007/s00339-019-2970-510.1007/s00339-019-2970-5 ↗
25. 10.1021/ja500330a10.1021/ja500330a ↗
26. 10.1021/acs.chemmater.1c0217410.1021/acs.chemmater.1c02174 ↗
27. 10.1039/b801892h10.1039/b801892h ↗
28. 10.1107/S002188981300519010.1107/S0021889813005190 ↗
29. 10.1088/0953-8984/19/33/33521910.1088/0953-8984/19/33/335219 ↗
30. 10.1021/ja00479a02110.1021/ja00479a021 ↗
31. 10.1088/0022-3719/15/25/02210.1088/0022-3719/15/25/022 ↗
32. 10.1051/jphyslet:0198200430702330010.1051/jphyslet:01982004307023300 ↗
33. 10.1038/s41467-022-28886-510.1038/s41467-022-28886-5 ↗
34. 10.1039/C0JM02381G10.1039/C0JM02381G ↗
35. Hauser A. · 2004 · 234 · 15510.1007/b95416 ↗
36. 10.1021/ic50215a02910.1021/ic50215a029 ↗
37. 10.1021/ic801165b10.1021/ic801165b ↗
38. 10.1021/ja402674x10.1021/ja402674x ↗
39. 10.1021/ic302533b10.1021/ic302533b ↗
40. 10.1103/PhysRevLett.100.02060310.1103/PhysRevLett.100.020603 ↗
41. 10.1021/acs.jctc.7b0011810.1021/acs.jctc.7b00118 ↗
42. 10.1103/PhysRev.136.B86410.1103/PhysRev.136.B864 ↗
43. 10.1103/PhysRev.140.A113310.1103/PhysRev.140.A1133 ↗