DataVXChemistry of MaterialsPaper
journal article·2024-01-23

Large-Scale and Rapid Processing of 3D COFs via 3D-Controlled Reaction–Diffusion Zones

Michele Mattera, Anh Tuan Ngo, João Pedro Vale, Carlos Franco, Semih Sevim, Maria Guix, Roc Matheu, Tiago Sotto Mayor, Salvador Pané, Josep Puigmartí-Luis

Chemistry of Materials· Volume 36· Issue 2
Publisher page
Source abstract

Abstract

Covalent organic frameworks (COFs) are an emerging class of two-dimensional (2D) or three-dimensional (3D) porous structures. Most COFs are typically prepared via solvothermal methods involving long reaction times (>12 h) that generally result in unprocessable powders, significantly hindering their straightforward integration into devices and applications. Current processing methods for 2D COFs have not been implemented for 3D COFs, probably due to the lack of preassembly mechanisms among the 3D COF precursors during synthesis. Here, we report a pioneering synthetic environment that achieves two objectives: precise control over the reaction time of 3D COF precursors through controlled diffusion, ensuring the absence of turbulent mixing, and the ability to fine-tune the specific reaction zone where the reaction and controlled diffusion of the 3D COF precursors will occur. We further demonstrate that controlling these two features in 3D creates an unparalleled synthetic environment, allowing for a rapid one-pot synthesis of 3D COFs, with their formation occurring in less than a minute. Additionally, this approach yields self-standing 3D COF fibers on a centimeter scale, showcasing the versatility and potential of the approach presented for scalable production of 3D COFs as well as for their seamless integration into devices and patterning strategies.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departament de Ciència dels Materials i Química Física, Institut de Química Teòrica i Computacional, University of Barcelona (UB), 08028 Barcelona, Spain

Transport Phenomena Research Centre (CEFT), Engineering Faculty of Porto University, 4200-465 Porto, Portugal

Associate Laboratory in Chemical Engineering (ALiCE), Engineering Faculty of Porto University, 4200-465 Porto, Portugal

Institute of Robotics and Intelligent Systems, ETH Zurich, Tannenstrasse 3, Zurich CH 8092, Switzerland

Departament de Química Inorgànica i Orgànica, Institut de Química Teòrica i Computacional, University of Barcelona (UB), 08028 Barcelona, Spain

Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg. Lluís Companys 23, 08010 Barcelona, Spain

Funding

Ministerio de Asuntos Econ?micos y Transformaci?n Digital, Gobierno de Espa?a · Schweizerischer Nationalfonds zur F?rderung der Wissenschaftlichen Forschung · 'la Caixa' Foundation · H2020 Future and Emerging Technologies · H2020 LEIT Biotechnology · Funda??o para a Ci?ncia e a Tecnologia · Agencia Estatal de Investigaci?n,Ministerio de Ciencia, Innovaci?n y Universidades

References (41)

Show source-provided references
1. 10.1126/science.112041110.1126/science.1120411 ↗
2. 10.1126/science.aal158510.1126/science.aal1585 ↗
3. 10.1002/anie.20190429110.1002/anie.201904291 ↗
4. 10.1039/D0CS01027H10.1039/D0CS01027H ↗
5. 10.3390/molecules2207114910.3390/molecules22071149 ↗
6. 10.1016/j.memsci.2023.12167910.1016/j.memsci.2023.121679 ↗
7. 10.1016/j.chemosphere.2021.13171010.1016/j.chemosphere.2021.131710 ↗
8. 10.1016/j.cej.2022.13511710.1016/j.cej.2022.135117 ↗
9. 10.1021/acs.chemmater.1c0238210.1021/acs.chemmater.1c02382 ↗
10. 10.1039/D1CC01857D10.1039/D1CC01857D ↗
11. 10.1016/j.memsci.2020.11784110.1016/j.memsci.2020.117841 ↗
12. 10.1039/D3RA02202A10.1039/D3RA02202A ↗
13. 10.1039/d0cc02907f10.1039/d0cc02907f ↗
14. 10.1039/C5CC06742A10.1039/C5CC06742A ↗
15. 10.1021/acs.chemmater.1c0112210.1021/acs.chemmater.1c01122 ↗
16. 10.1039/C5CC10221A10.1039/C5CC10221A ↗
17. 10.1021/jacs.6b0466910.1021/jacs.6b04669 ↗
18. 10.1021/jacs.2c0230110.1021/jacs.2c02301 ↗
19. 10.1021/jacs.3c0440910.1021/jacs.3c04409 ↗
20. 10.1039/D3SC01367G10.1039/D3SC01367G ↗
21. 10.1103/PhysRevLett.80.386310.1103/PhysRevLett.80.3863 ↗
22. 10.1016/j.apmt.2020.10063210.1016/j.apmt.2020.100632 ↗
23. 10.1002/adma.20090342810.1002/adma.200903428 ↗
24. 10.1039/C6CC04013F10.1039/C6CC04013F ↗
25. 10.1002/anie.20210161110.1002/anie.202101611 ↗
26. 10.1002/adma.20150646210.1002/adma.201506462 ↗
27. 10.1021/ja809625610.1021/ja8096256 ↗
28. 10.1126/science.aat767910.1126/science.aat7679 ↗
29. 10.1021/jacs.8b0316910.1021/jacs.8b03169 ↗
30. 10.1038/s41467-020-19858-810.1038/s41467-020-19858-8 ↗
31. 10.1021/acsami.1c2098910.1021/acsami.1c20989 ↗
32. Bird R. B. S. · 1960
33. 10.1039/C8CC09571J10.1039/C8CC09571J ↗
34. 10.1021/ja409033p10.1021/ja409033p ↗
35. 10.1002/cey2.19910.1002/cey2.199 ↗
36. 10.1021/acsnano.2c1134610.1021/acsnano.2c11346 ↗
37. 10.1002/admt.20220049210.1002/admt.202200492 ↗
38. 10.1002/advs.20200137910.1002/advs.202001379 ↗
39. 10.1002/adma.20170565110.1002/adma.201705651 ↗
40. 10.1002/adfm.20190624410.1002/adfm.201906244 ↗
41. 10.1016/j.sna.2020.11191610.1016/j.sna.2020.111916 ↗