Azide-Functionalized Nanoclusters via a Ligand-Induced Rearrangement
Source abstract
Abstract
Herein, we report a methodology to prepare atomically precise, azide-functionalized nanoclusters based on a ligand-induced rearrangement. Three surface-clickable nanoclusters, including a “waist”-clickable cluster, Au25(PPh3)10(SPhN3)5Cl2, and two “whole-body” clickable clusters, Au28(SPhN3)20 and Au36(SPhN3)24, have been prepared and characterized. This work presents a facile and powerful strategy to generate metal nanoclusters with surface ligands of well-defined spatial orientations and numbers, which hopefully can promote various bioconjugation strategies and downstream applications.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Gold and Silver Nanoparticles Synthesis and Applications · Advanced Nanomaterials in Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Chemical Biology, Northeastern University, Boston, Massachusetts 02115, United States
Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui University, Hefei, Anhui 230601, P. R. China
Funding
Ministry of Education of the People's Republic of China · Anhui Department of Education · National Natural Science Foundation of China · Division of Materials Research
References (82)
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