Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks
Source abstract
Abstract
Designing new ultraviolet nonlinear optical (NLO) crystals with strong second-harmonic generation (SHG) response and a deep ultraviolet cutoff edge is an unremitting pursuit of scientific researchers, accompanied by the key issues of how to realize a noncentrosymmetric structure with the ideal arrangement of ultraviolet NLO-active genes. Herein, a strategy that creates halogen-centered secondary building blocks with rare-earth atoms was used for further design, and we synthesized rationally an unprecedented NLO crystal Cs 2 La 2 B 10 O 17 Cl 4 exhibiting the largest SHG response (2.1 × KDP) among borates with [B 5 O 11 ] as the fundamental building blocks. The unique role of Cl-centered secondary building blocks in regulating the arrangement of the B–O framework and enhancing nonlinearity was discussed in detail, which will bring the researcher a perspective in designing new NLO crystals.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Crystal Structures and Properties · Crystal structures of chemical compounds · Inorganic Fluorides and Related Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Funding
National Key Research and Development Program of China · Science and Technology Department of Xinjiang Uyghur Autonomous Region · West Light Foundation of the Chinese Academy of Sciences · National Natural Science Foundation of China · Chinese Academy of Sciences · Tianshan Talents - Young Science and Technology Top Talents Project
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