journal article·2022-10-11

Light-Induced Charge Transfer to Achieve Deep-Red Emission in SrSc2O4:Bi toward Multiple Optical Applications

Yi Wei, Chen Heng, Hang Yang, Peipei Dang, Maxim S. Molokeev, Lixin Ning, Guogang Li

Chemistry of Materials· Volume 34· Issue 19
Publisher page

Abstract

Bismuth (Bi) is used for luminescent materials due to its unique optical performance, but deep-red light from Bi-doped materials is rarely reported. In particular, establishing a design principle for Bi-doped red materials is considered to be a significant challenge. Herein, using a deep-red SrSc2O4:Bi material featuring Bi–Bi pair emission, light-induced charge-transfer from BiSc3+–BiSr3+ to BiSc4+–BiSr2+ enables the realization of Bi2+2P3/2(1) → 2S1/2 deep-red emission. Intriguingly, SrSc2O4:Bi displays an excellent zero-thermal-quenching performance from 298 to 423 K, with a peak intensity that retains 98% of the intensity at 298 K and an integrated intensity at 423 K that even reaches 110% of the initial intensity. The intriguing spectroscopic characteristics of SrSc2O4:Bi make it a promising candidate in the agricultural field, night-vision security, and the medical treatment area. This work advances the understanding of red luminescence in Bi-activated luminescent materials and thus can initiate more exploitation of red materials for emerging applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Perovskite Materials and Applications · Crystal Structures and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, Hubei 430074, China

Anhui Key Laboratory of Optoelectric Materials Science and Technology, Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Normal University, Wuhu, Anhui 241000, China

State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia

Siberian Federal University, Krasnoyarsk 660041, Russia

Department of Physics, Far Eastern State Transport University, Khabarovsk 680021, Russia

Zhejiang Institute, China University of Geosciences, Hangzhou, Zhejiang 311305, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Zhejiang Province

References (54)

Show source-provided references
1. 10.1021/acs.chemmater.0c0115110.1021/acs.chemmater.0c01151 ↗
2. 10.1038/s41586-018-0691-010.1038/s41586-018-0691-0 ↗
3. 10.1007/s12274-020-3026-z10.1007/s12274-020-3026-z ↗
4. 10.1021/jacs.5b0608010.1021/jacs.5b06080 ↗
5. 10.1126/science.aag270010.1126/science.aag2700 ↗
6. 10.1021/jacs.8b0476310.1021/jacs.8b04763 ↗
7. 10.1002/anie.20181336310.1002/anie.201813363 ↗
8. 10.1038/nmat401210.1038/nmat4012 ↗
9. 10.1126/sciadv.aao420410.1126/sciadv.aao4204 ↗
10. 10.1002/adfm.20190099110.1002/adfm.201900991 ↗
11. 10.1002/adfm.20210392710.1002/adfm.202103927 ↗
12. 10.1021/acs.chemmater.0c0224310.1021/acs.chemmater.0c02243 ↗
13. 10.1038/s41467-019-13293-010.1038/s41467-019-13293-0 ↗
14. 10.1002/anie.20190578710.1002/anie.201905787 ↗
15. 10.1002/anie.20190317810.1002/anie.201903178 ↗
16. 10.1002/anie.20140252010.1002/anie.201402520 ↗
17. 10.1002/adom.20210237310.1002/adom.202102373 ↗
18. 10.1039/D0TC05960A10.1039/D0TC05960A ↗
19. 10.1002/adom.20200103710.1002/adom.202001037 ↗
20. 10.1021/acs.chemmater.7b0297910.1021/acs.chemmater.7b02979 ↗
21. 10.1021/acs.chemmater.7b0315110.1021/acs.chemmater.7b03151 ↗
22. 10.1016/j.cej.2021.13426510.1016/j.cej.2021.134265 ↗
23. 10.1021/acs.chemmater.9b0434110.1021/acs.chemmater.9b04341 ↗
24. 10.1021/acssuschemeng.0c0659310.1021/acssuschemeng.0c06593 ↗
25. 10.1039/C9TC06640C10.1039/C9TC06640C ↗
26. 10.1039/C6TC03524H10.1039/C6TC03524H ↗
27. 10.1021/acs.chemmater.0c0281410.1021/acs.chemmater.0c02814 ↗
28. 10.1002/adom.20220015010.1002/adom.202200150 ↗
29. 10.1039/C4TC01623H10.1039/C4TC01623H ↗
30. 10.1021/jp408196510.1021/jp4081965 ↗
31. 10.1039/C6TC03880H10.1039/C6TC03880H ↗
32. 10.1039/C9TC01385G10.1039/C9TC01385G ↗
33. 10.1021/acs.jpcc.6b0531210.1021/acs.jpcc.6b05312 ↗
34. 10.1021/acs.inorgchem.5b0088710.1021/acs.inorgchem.5b00887 ↗
35. 10.1021/jp502996t10.1021/jp502996t ↗
36. 10.1021/acs.inorgchem.7b0056410.1021/acs.inorgchem.7b00564 ↗
37. 10.1364/OE.18.01285210.1364/OE.18.012852 ↗
38. 10.1039/c3tc31069h10.1039/c3tc31069h ↗
39. 10.1016/j.jlumin.2018.02.03510.1016/j.jlumin.2018.02.035 ↗
40. 10.1107/S056773947600155110.1107/S0567739476001551 ↗
41. 10.1007/s10854-018-8688-x10.1007/s10854-018-8688-x ↗
42. 10.1111/j.1551-2916.2009.03590.x10.1111/j.1551-2916.2009.03590.x ↗
43. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗
44. 10.1016/j.optmat.2017.02.03210.1016/j.optmat.2017.02.032 ↗
45. 10.1063/1.156406010.1063/1.1564060 ↗
46. 10.1063/1.240466310.1063/1.2404663 ↗
47. 10.1103/PhysRevB.104.11510110.1103/PhysRevB.104.115101 ↗
48. 10.1038/nmat484310.1038/nmat4843 ↗
49. 10.1016/j.mattod.2020.04.03210.1016/j.mattod.2020.04.032 ↗
50. 10.1038/s41377-019-0126-110.1038/s41377-019-0126-1 ↗
51. 10.1021/acsami.8b0275810.1021/acsami.8b02758 ↗
52. 10.1021/jacs.8b0602110.1021/jacs.8b06021 ↗
53. 10.1002/adom.20210117310.1002/adom.202101173 ↗
54. 10.1021/acs.inorgchem.1c0247410.1021/acs.inorgchem.1c02474 ↗