Impact of Ni–Mn–Co–Al-Based Cathode Material Composition on the Sintering with Garnet Solid Electrolytes for All-Solid-State Batteries
Source abstract
Abstract
High Resolution Image Download MS PowerPoint Slide A systematic and comprehensive study of the thermal stability of the cathode active materials LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC111), LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622), LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811), and LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA) in combination with the garnet solid electrolyte Li 6.45 La 3 Zr 1.6 Ta 0.4 Al 0.05 O 12 was performed, and the respective thermal stability limits in air were assessed. Compared to prior studies on such material mixtures, additional Zr-containing secondary phases were detected, which had not been taken into consideration in a previously published work. Here, these phases were successfully identified for the first time by a combination of X-ray diffraction, Raman spectroscopy, and microstructural analysis.
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Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Faculty of Engineering and Center for Nanointegration Duisburg-Essen (CENIDE), Universität Duisburg-Essen, Lotharstraße 1, 47057 Duisburg, Germany
Helmholtz Institute Münster: Ionics in Energy Storage (IEK-12), Forschungszentrum Jülich GmbH, Corrensstr. 46, 48149 Münster, Germany
Jülich Aachen Research Alliance: JARA-Energy, 52425 Jülich, Germany
Funding
Bundesministerium f?r Bildung und Forschung · Bundesministerium f?r Wirtschaft und Klimaschutz · Helmholtz Association
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