Pore-Nanospace Engineering of Mixed-Ligand Metal–Organic Frameworks for High Adsorption of Hydrofluorocarbons and Hydrochlorofluorocarbons
Source abstract
Abstract
The isostructural mixed-ligand metal–organic frameworks (MOFs), LIFM-66, 66/67-mix, and 67, have been constructed via organic-linker modification and variation to introduce different portions of functional groups into the pore-nanospaces with tunable surface areas. Adsorption measurements of hydrofluorocarbon (HFC) and hydrochlorofluorocarbon (HCFC) with these MOFs reveal a record high uptake of R134a (1.09–1.14 g g–1) and an ultrahigh uptake of R22 (0.85–0.96 g g–1) under ordinary conditions of room temperature and atmospheric pressure. Noteworthily, the adsorption performance of greenhouse gases CO2, R134a, and R22 can be finely regulated by introduced methyl groups, which has been elucidated by molecular modeling and transient breakthrough simulations/experiments, demonstrating an effective protocol of pore-nanospace engineering through rational design of mixed-ligand MOFs for HFC and HCFC capture, sequestration, and reclamation.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Carbon Dioxide Capture Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China
Van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida 33620, United States
School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, P. R. China
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
Funding
Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · China Postdoctoral Science Foundation · National Natural Science Foundation of China
References (59)
Show source-provided references
1. Casper, J. K. Greenhouse Gases: Worldwide Impacts; Infobase Publishing, 2009; pp. 1–270.
2. Solomon S. · 2007
3. Kirsch, P. Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications; Wiley-VCH publishing, 2013; pp. 1–108.10.1002/9783527651351 ↗
4. 10.1038/ngeo210910.1038/ngeo2109 ↗
5. 10.1016/j.rser.2009.08.00110.1016/j.rser.2009.08.001 ↗
6. 10.1016/j.chemosphere.2008.04.02910.1016/j.chemosphere.2008.04.029 ↗
7. 10.1039/d0cs00258e10.1039/d0cs00258e ↗
8. 10.1021/acs.chemrev.9b0071910.1021/acs.chemrev.9b00719 ↗
9. 10.1002/anie.20150514910.1002/anie.201505149 ↗
10. 10.1039/D0MA00083C10.1039/D0MA00083C ↗
11. 10.1038/ncomms536810.1038/ncomms5368 ↗
12. 10.1002/slct.20160068910.1002/slct.201600689 ↗
13. 10.1016/0198-0149(88)90033-710.1016/0198-0149(88)90033-7 ↗
14. 10.1016/j.dsr.2008.03.01410.1016/j.dsr.2008.03.014 ↗
15. 10.1016/S0304-4203(02)00015-410.1016/S0304-4203(02)00015-4 ↗
16. 10.1039/d0cs00075b10.1039/d0cs00075b ↗
17. Wai H. C. · Adv. Mater. Res. · 2013 · 795 · 9610.4028/www.scientific.net/AMR.795.96 ↗
18. 10.1039/c7cs00885f10.1039/c7cs00885f ↗
19. 10.1039/c8cs00829a10.1039/c8cs00829a ↗
20. 10.1039/c9cs00756c10.1039/c9cs00756c ↗
21. 10.1039/c7cs00153c10.1039/c7cs00153c ↗
22. 10.1073/pnas.090971810610.1073/pnas.0909718106 ↗
23. 10.1021/cr200327210.1021/cr2003272 ↗
24. 10.1039/C6TA05098K10.1039/C6TA05098K ↗
25. 10.1126/science.119216010.1126/science.1192160 ↗
26. 10.1021/ar100023y10.1021/ar100023y ↗
27. 10.1038/ncomms1535610.1038/ncomms15356 ↗
28. 10.1039/c7cs00782e10.1039/c7cs00782e ↗
29. 10.1039/C6TA10281F10.1039/C6TA10281F ↗
30. 10.1002/adfm.20200023810.1002/adfm.202000238 ↗
31. 10.1039/c4sc03985h10.1039/c4sc03985h ↗
32. 10.1002/adma.20170435010.1002/adma.201704350 ↗
33. 10.1021/jacs.9b1196310.1021/jacs.9b11963 ↗
34. 10.1021/jacs.7b0487210.1021/jacs.7b04872 ↗
35. 10.1002/anie.20210233710.1002/anie.202102337 ↗
36. 10.1021/acsaem.8b0128210.1021/acsaem.8b01282 ↗
37. 10.1038/ncomms613110.1038/ncomms6131 ↗
38. 10.1021/ja077526510.1021/ja0775265 ↗
39. 10.1039/c7cc06352k10.1039/c7cc06352k ↗
40. 10.1002/chem.20160603810.1002/chem.201606038 ↗
41. 10.1126/science.aaz430410.1126/science.aaz4304 ↗
42. 10.1093/nsr/nwx01310.1093/nsr/nwx013 ↗
43. 10.1126/science.118176110.1126/science.1181761 ↗
44. 10.1021/ja512762r10.1021/ja512762r ↗
45. 10.1039/c9cs00250b10.1039/c9cs00250b ↗
46. 10.1021/jacs.7b0739210.1021/jacs.7b07392 ↗
47. 10.1021/jacs.7b0311310.1021/jacs.7b03113 ↗
48. 10.1021/jacs.7b0132010.1021/jacs.7b01320 ↗
49. 10.1021/jacs.9b0012210.1021/jacs.9b00122 ↗
50. 10.1021/jacs.6b0326310.1021/jacs.6b03263 ↗
51. 10.1002/anie.20160402310.1002/anie.201604023 ↗
52. 10.1016/j.chempr.2018.08.02510.1016/j.chempr.2018.08.025 ↗
53. 10.1021/ar500125m10.1021/ar500125m ↗
54. 10.1016/j.ijrefrig.2009.03.01010.1016/j.ijrefrig.2009.03.010 ↗
55. 10.1002/aic.69011012510.1002/aic.690110125 ↗
56. 10.1023/A:100891470388410.1023/A:1008914703884 ↗
57. 10.1016/j.micromeso.2013.10.02610.1016/j.micromeso.2013.10.026 ↗
58. 10.1039/C5RA07830J10.1039/C5RA07830J ↗
59. 10.1016/j.micromeso.2012.02.02110.1016/j.micromeso.2012.02.021 ↗