journal article·2022-08-09

Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies

Harrison A. Mills, Christopher G. Jones, Kierstyn P. Anderson, Austin D. Ready, Peter I. Djurovich, Saeed I. Khan, J. Nathan Hohman, Hosea M. Nelson, Alexander M. Spokoyny

Chemistry of Materials· Volume 34· Issue 15
Publisher page

Abstract

Herein, we report the use of sterically invariant carborane-based chalcogenols, containing exopolyhedral B–Se or B–S bonds, as ligands for the formation of photoluminescent copper(I)-based metal–organic chalcogenolate assemblies (MOCHAs). We show that precise tuning of the carborane dipole by changing the carborane isomer from meta to ortho allows for control over the MOCHA morphology and regulation of the resulting photophysical properties. Furthermore, microcrystal electron diffraction (MicroED) has been demonstrated as a powerful tool for metal chalcogenide structure elucidation. Through the use of MicroED, one of the isolated materials is determined to consist of zero-dimensional Cu4(Se–C2B10H11)4 clusters with an unprecedented Cu4Se4 geometry.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Boron Compounds in Chemistry · Nanocluster Synthesis and Applications · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States

Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States

Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States

Institute of Materials Science and the Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269, United States

California NanoSystems Institute (CNSI), University of California, Los Angeles, Los Angeles, California 90095, United States

Funding

University of California, Los Angeles · Camille and Henry Dreyfus Foundation · National Science Foundation

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