Templated Solvent-Free Powder Synthesis and MOF-CVD Films of the Ultramicroporous Metal–Organic Framework α-Magnesium Formate
Source abstract
Abstract
Because of their molecular sieving properties, metal–organic frameworks have a high potential for application in gas storage, separation, and sensing. However, their real-world implementation will require robust and low-cost synthetic approaches. We herein report the solvent-free synthesis of ultramicroporous α-magnesium formate (α-MgFm) based on the solid–vapor reaction of magnesium oxide (MgO) and formic acid and establish the requirement for a structure-directing agent. Translated into a chemical vapor deposition protocol, this method enables the fabrication of high-quality, pinhole-free films of α-MgFm.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnesium Oxide Properties and Applications · X-ray Diffraction in Crystallography
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Microbial and Molecular Systems, Centre for Membrane Separation, Adsorption, Catalysis and Spectroscopy, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium
Research Group of Electrochemical and Surface Engineering, Department of Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2, Brussels 1050, Belgium
Funding
KU Leuven · H2020 Future and Emerging Technologies · Fonds Wetenschappelijk Onderzoek · H2020 Research Infrastructures · H2020 European Research Council
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