Control of π−π Interactions in Epitaxial Films of Platinum(II) Octaethyl Porphyrin
Source abstract
Abstract
Epitaxial thin films of Pt(II) octaethyl porphyrin were grown on the cleavage surface of graphite and potassium hydrogen phthalate. The structure of the films was characterized by high resolution atomic force microscopy, showing that the two substrates template the growth of two layered phases with dramatic structural differences, strongly influencing π-stacking of adjacent molecules. The impact of these characteristics on the electronic structure of the film phases is illustrated by a thorough optical investigation.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Molecular Junctions and Nanostructures · Porphyrin and Phthalocyanine Chemistry · Organic Electronics and Photovoltaics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Geological Sciences and Geotechnologies, Università degli Studi di Milano Bicocca, Piazza della Scienza 4, I-20126, Milano, Italy
Department of Materials Science, Università degli Studi di Milano Bicocca, Via R. Cozzi 53, I-20125, Milano, Italy
References (31)
Show source-provided references
1. Noh Y.-Y. · Adv. Mater. · 2003 · 15 · 69910.1002/adma.200304005 ↗
2. Shao Y. · Adv. Mater. · 2005 · 17 · 284110.1002/adma.200501297 ↗
3. Kwong R. C. · Chem. Mater. · 1999 · 11 · 370910.1021/cm9906248 ↗
4. Baldo M. · Nature · 1998 · 395 · 15110.1038/25954 ↗
5. Monguzzi A. · Phys. Rev. B · 2008 · 78 · 19511210.1103/PhysRevB.78.195112 ↗
6. de Oteyza D. G. · Chem. Mater. · 2006 · 18 · 421210.1021/cm061172j ↗
7. Suto K. · Langmuir · 2006 · 22 · 1076610.1021/la061257z ↗
8. Oncel N. · Appl. Phys. Lett. · 2008 · 92 · 13330510.1063/1.2904622 ↗
9. Campione M. · J. Am. Chem. Soc. · 2006 · 128 · 1337810.1021/ja058771w ↗
10. Sassella A. · Riv. Nuovo Cimento · 2008 · 32 · 457
11. Campione M. · Chem. Mater. · 2009 · 21 · 485910.1021/cm901463u ↗
12. Forker R. · Adv. Mater. · 2008 · 20 · 445010.1002/adma.200801112 ↗
13. Koller G. · Nano Lett. · 2006 · 6 · 120710.1021/nl060629l ↗
14. Haber T. · Physica E · 2008 · 41 · 13310.1016/j.physe.2008.06.014 ↗
15. Graswinckel W. S. · Cryst. Growth Des. · 2007 · 7 · 24310.1021/cg0602257 ↗
16. Milgrom L. R. · Polyhedron · 1988 · 7 · 5710.1016/S0277-5387(00)81182-1 ↗
17. Chen W. · Chem. Commun. · 2008 · 427610.1039/b805788e ↗
18. Eremtchenko M. · Nature · 2003 · 425 · 60210.1038/nature01901 ↗
19. Liu H. W. · J. Cryst. Growth · 2010 · 312 · 96710.1016/j.jcrysgro.2009.12.066 ↗
20. Bussolotti F. · Phys. Rev. B · 2009 · 79 · 24541010.1103/PhysRevB.79.245410 ↗
21. Gouterman M. · J. Mol. Spectrosc. · 1961 · 6 · 13810.1016/0022-2852(61)90236-3 ↗
22. Bansal A. K. · Chem. Phys. · 2006 · 330 · 11810.1016/j.chemphys.2006.08.002 ↗
23. Puntambekar K. · Adv. Funct. Mater. · 2006 · 16 · 87910.1002/adfm.200500816 ↗
24. Che C.-M. · Chem. Asian J. · 2008 · 3 · 109210.1002/asia.200800011 ↗
25. Pak R. · Acta Crystallogr., Sect. C · 1991 · 47 · 43110.1107/S0108270190008010 ↗
26. Dienel T. · J. Lumin. · 2004 · 110 · 25310.1016/j.jlumin.2004.08.017 ↗
27. Kalinowski J. · J. Chem. Phys. · 2005 · 122 · 15471010.1063/1.1878612 ↗
28. Tsuboi T. · Thin Solid Films · 2006 · 496 · 67410.1016/j.tsf.2005.09.078 ↗
29. Pope M. · 1982
30. Minari T. · Appl. Phys. Lett. · 2007 · 91 · 12350110.1063/1.2786020 ↗
31. da Silva Filho D. A. · Adv. Mater. · 2005 · 17 · 107210.1002/adma.200401866 ↗