Understanding the Chemistry of Metal Oxide to Metal–Organic Framework Reactions for Morphology Control

Ralph Freund; Arianna E. Lanza; Stefano Canossa; Mauro Gemmi; Joanna Goscianska; Valentina Cauda; Martin Oschatz; Stefan Wuttke

doi:10.1021/acs.chemmater.2c02946

journal article·2023-03-14

Understanding the Chemistry of Metal Oxide to Metal–Organic Framework Reactions for Morphology Control

Ralph Freund, Arianna E. Lanza, Stefano Canossa, Mauro Gemmi, Joanna Goscianska, Valentina Cauda, Martin Oschatz, Stefan Wuttke

Chemistry of Materials· Volume 35· Issue 5

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Source abstract

Abstract

Metal–organic frameworks (MOFs) are a class of porous materials that have been thoroughly investigated in the past two decades; however, three-dimensional (3D) morphological control is still not established to an adequate degree. The use of metal oxides (MOs) with controllable morphology as precursors is a promising approach to overcome this limitation. Here, we investigate the formation of MOFs from different MOs and carry out a detailed case study to rationalize the factors governing the conversion of zinc oxide nanowires into ZIF-8 with the same morphology. This knowledge is then applied to generate complex 3D ZIF-8 and ZnO@ZIF-8 composite structures from different ZnO precursors. In addition, we show that this approach can be used to access new MOF structures, which are not achievable by standard synthetic methods. This study showcases how a deep understanding of the MO-to-MOF conversion can be used for the fabrication of MOF materials with precisely tailored morphology.

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials Composites

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Nanoplatforms for cancer theranostics · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chemistry Department and Center for NanoScience, University of Munich (LMU), 80539 Munich, Germany

Istituto Italiano di Tecnologia, Center for Materials Interfaces, Electron Crystallography, Viale Rinaldo Piaggio 34, 56025 Pontedera, Italy

Department of Nanochemistry, Max Planck Institute for Solid State Research, 70569 Stuttgart, Germany

Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznan, Poland

Department of Applied Science and Technology, Politecnico di Torino, 10129 Torino, Italy

Center for Energy and Environmental Chemistry Jena (CEEC Jena), Institute for Technical Chemistry and Environmental Chemistry, Friedrich-Schiller-University Jena, Philosophenweg 7a, 07743 Jena, Germany

BCMaterials, Basque Center for Materials, UPV/EHU Science Park, 48940 Leioa, Spain

Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain

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