DataVXChemistry of MaterialsPaper
journal article·2015-10-13

High Pressure Synthesis of All-Transoid Polycarbonyl [—(C═O)—]n in a Zeolite

Mario Santoro, Kamil Dziubek, Demetrio Scelta, Matteo Ceppatelli, Federico A. Gorelli, Roberto Bini, Jean-Marc Thibaud, Francesco Di Renzo, Olivier Cambon, Jerome Rouquette, Patrick Hermet, Arie van der Lee, Julien Haines

Chemistry of Materials· Volume 27· Issue 19
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Source abstract

Abstract

A study was conducted to demonstrate the synthesis of high pressure synthesis of all-transoid polycarbonyl [-(C=O)]n in a zeolite. The study also demonstrated the feasibility of inducing the self-assembly of dense CO in the spatially subnano-confined region of the channels of an electrically neutral, non-catalytic, hydrophobic, and all SiO2 zeolite silicalite. It was observed that the insertion of simple guest molecules, such as Ar and CO2 in the channels of this zeolite deactivated the pressure induced amorphization of the framework up to at least 25 GPa.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Synthetic Organic Chemistry Methods · Catalysis and Oxidation Reactions · Organometallic Complex Synthesis and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Istituto Nazionale di Ottica, CNR-INO, 50019 Sesto Fiorentino, Italy

European Laboratory for Non Linear Spectroscopy (LENS), 50019 Sesto Fiorentino, Italy

Faculty of Chemistry, Adam Mickiewicz University, Umultowska 89b, 61-614 Poznań, Poland

Istituto di Chimica dei Composti OrganoMetallici, CNR-ICCOM, 50019 Sesto Fiorentino, Italy

Dipartimento di Chimica “Ugo Schiff″, Università degli Studi di Firenze, 50019 Sesto Fiorentino, Italy

Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-Université de Montpellier-ENSCM, 34095 Montpellier, Cedex 5, France

Institut Européen des Membranes de Montpellier, UMR 5635 CNRS-Université de Montpellier, 34095 Montpellier, Cedex 5, France

Funding

Agence Nationale de la Recherche · Ministerstwo Nauki i Szkolnictwa Wyzszego

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