Steering Two-Dimensional Porous Networks with σ-Hole Interactions of Br···S and Br···Br
Source abstract
Abstract
The self-assembly of 3,10-dibromo-perylo[1,12-b,c,d]thiophene on Ag(111) leads to three types of ordered porous networks: honeycomb PN1, Kagome PN2, and hybrid PN3. Detailed experimental and theoretical analyses confirm the thermal stability order of the three constructed porous networks. High-resolution scanning tunneling microscopy images indicate the importance of two σ-hole interactions of Br···S and Br···Br in steering two-dimensional molecular assembly on metal surfaces.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Surface Chemistry and Catalysis · Covalent Organic Framework Applications · Advanced Chemical Physics Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Research Institute of Aerospace Special Materials and Processing Technology, Beijing 100074, China
California NanoSystems Institute, Department of Chemistry and Biochemistry, and Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, United States
Funding
National Natural Science Foundation of China · Ministry of Science and Technology
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