journal article·2009-10-13

Crystal Structure of Sr0.4Ce0.4TiO3 Ceramics

Rick Ubic, Ganesanpotti Subodh, Delphine Gout, Mailadil T. Sebastian, Thomas Proffen

Chemistry of Materials· Volume 21· Issue 19
Publisher page

Abstract

A cerium-doped SrTiO 3 compound with the composition Sr 0.4 Ce 0.4 TiO 3 has been produced by conventional solid-state processing. The structure of this compound was analyzed by X-ray, electron, and neutron diffraction. While no superlattice can be observed via X-ray diffraction, both electron and neutron diffraction show evidence of a noncubic supercell caused by antiphase tilting of oxygen octahedra. The most likely space group is C 2/ c, corresponding to an a − b − b − tilt system. Octahedra are tilted by ∼5° about the pseudo-cubic a -axis and ∼1.5° about the pseudo-cubic b - and c -axes.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science & Engineering, College of Engineering, Boise State University, Boise, Idaho 83725-2075

Materials and Minerals Division, Institute of Interdisciplinary Sciences and Technology, Trivandrum 695 019, India

Jülich Center for Neutron Science−SNS, Forschungszentrum Jülich, 52425 Jülich, Germany

Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 38371

Los Alamos Neutron Science Center, Los Alamos, New Mexico 87545

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