Toward Design Rules of Metal–Organic Frameworks for Adsorption Cooling: Effect of Topology on the Ethanol Working Capacity
Source abstract
Abstract
Using combined experimental and computational approaches, we studied the adsorption behavior of ethanol in a series of metal-organic frameworks (MOFs) with similar building blocks but different topologies and tested their performance as adsorption coolers. Here, we analyzed the relationship between the MOF structures and their ethanol working capacities under different working conditions. Molecular-level insights into the microscopic adsorption behavior were also gained from atomistic simulations. Based on the structure-property relationships that we found, we selected another MOF (MOF-525) for study, and our experiments and simulations both showed superior ethanol working capacity for this MOF, which verified our design rules.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Carbon Dioxide Capture Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu 210009, P. R. China
Future Mobility Research Department, Toyota Research Institute of North America, Ann Arbor, Michigan 48105, United States
Funding
Basic Energy Sciences
References (28)
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