journal article·2022-04-26

A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

Yingshuang Sun, Chensheng Lin, Haotian Tian, Yuqiao Zhou, Jindong Chen, Shunda Yang, Ning Ye, Min Luo

Chemistry of Materials· Volume 34· Issue 8
Publisher page

Abstract

A series of new noncentrosymmetric beryllium sulfates, A2BeS2O8 (A = NH4, K, Rb, Cs), were rationally designed and synthesized based on the parent borophosphates KMBP2O8 (M = Sr, Ba). Owing to the rigid three-dimensional frameworks, A2BeS2O8 (A = NH4, K, Rb, Cs) showed the high thermodynamic stabilities. Among them, A2BeS2O8 (A = K, Rb, Cs) exhibited the highest thermodynamic stabilities among all the reported nonlinear (NLO) sulfates. In addition, benefiting from the flexible Be–O bonds within [BeO4], A2BeS2O8 (A = NH4, K, Rb, Cs) exhibited the enhanced second harmonic generation (SHG) responses, which were about 3 to 5 times that of parent borophosphates. Furthermore, they possessed a moderate birefringence of 0.013–0.024 and could be transparent down to the deep ultraviolet (DUV) region below 200 nm. This work indicated that the basic building blocks in borophosphates and beryllium sulfates were potentially interchangeable, which provided the possibility for a further study of new NLO crystals.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Crystal Structures and Properties · Solid-state spectroscopy and crystallography · Crystal structures of chemical compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

University of Chinese Academy of Sciences, Beijing 100049, China

Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, Tianjin University of Technology, Tianjin 300384, China

Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350002, China

Funding

Natural Science Foundation of Fujian Province · Youth Innovation Promotion Association of the Chinese Academy of Sciences · National Natural Science Foundation of China

References (59)

Show source-provided references
1. Chen C. · 201210.1002/9783527646388 ↗
2. 10.1038/nphoton.2006.9510.1038/nphoton.2006.95 ↗
3. 10.1038/457953a10.1038/457953a ↗
4. 10.1016/s1359-0286(96)80085-410.1016/s1359-0286(96)80085-4 ↗
5. 10.1002/adma.1995007011810.1002/adma.19950070118 ↗
6. 10.1002/anie.20200667110.1002/anie.202006671 ↗
7. 10.1016/0925-3467(95)00050-x10.1016/0925-3467(95)00050-x ↗
8. 10.1021/ja102737t10.1021/ja102737t ↗
9. 10.1021/ja204179g10.1021/ja204179g ↗
10. 10.1002/anie.20110396010.1002/anie.201103960 ↗
11. 10.1002/anie.20161223610.1002/anie.201612236 ↗
12. 10.1002/anie.20180372110.1002/anie.201803721 ↗
13. 10.1021/ja411272y10.1021/ja411272y ↗
14. 10.1021/jacs.8b1020910.1021/jacs.8b10209 ↗
15. 10.1021/ja504319x10.1021/ja504319x ↗
16. 10.1002/anie.20141177210.1002/anie.201411772 ↗
17. 10.1021/jacs.6b0605310.1021/jacs.6b06053 ↗
18. 10.1039/c7qi00548b10.1039/c7qi00548b ↗
19. 10.1039/c4tc02443e10.1039/c4tc02443e ↗
20. 10.1364/josab.21.00076110.1364/josab.21.000761 ↗
21. 10.1002/adma.20150395110.1002/adma.201503951 ↗
22. 10.1002/anie.20210210710.1002/anie.202102107 ↗
23. 10.1016/0022-3093(89)90281-010.1016/0022-3093(89)90281-0 ↗
24. 10.1524/zkri.1931.76.1.28910.1524/zkri.1931.76.1.289 ↗
25. 10.1107/s0365110x6300300510.1107/s0365110x63003005 ↗
26. 10.1002/anie.20210577710.1002/anie.202105777 ↗
27. 10.1021/ic900620x10.1021/ic900620x ↗
28. 10.1107/s205322961402421810.1107/s2053229614024218 ↗
29. 10.1107/s002188980202211210.1107/s0021889802022112 ↗
30. 10.1016/0025-5408(70)90112-110.1016/0025-5408(70)90112-1 ↗
31. Kubelka P. · Z. Technol. Phys. · 1931 · 12 · 593
32. 10.1039/c9ce01934k10.1039/c9ce01934k ↗
33. 10.1039/c9dt02512j10.1039/c9dt02512j ↗
34. 10.1063/1.165685710.1063/1.1656857 ↗
35. 10.1524/zkri.220.5.567.6507510.1524/zkri.220.5.567.65075 ↗
36. 10.1103/revmodphys.64.104510.1103/revmodphys.64.1045 ↗
37. 10.1103/physrevlett.100.13640610.1103/physrevlett.100.136406 ↗
38. 10.1103/physrevb.13.518810.1103/physrevb.13.5188 ↗
39. 10.1103/physrevb.41.154210.1103/physrevb.41.1542 ↗
40. 10.1021/acs.jpcc.7b1097210.1021/acs.jpcc.7b10972 ↗
41. 10.1103/physrevb.70.23511010.1103/physrevb.70.235110 ↗
42. 10.1021/jacs.9b0013810.1021/jacs.9b00138 ↗
43. 10.1039/c8tc04361b10.1039/c8tc04361b ↗
44. 10.1039/c9tc03105g10.1039/c9tc03105g ↗
45. 10.1002/anie.20190063710.1002/anie.201900637 ↗
46. 10.1039/c9tc01249d10.1039/c9tc01249d ↗
47. 10.1021/acs.inorgchem.1c0140110.1021/acs.inorgchem.1c01401 ↗
48. 10.1038/srep2520110.1038/srep25201 ↗
49. 10.1039/c4ce01658k10.1039/c4ce01658k ↗
50. 10.1021/cm040121o10.1021/cm040121o ↗
51. 10.1016/j.jcrysgro.2007.11.19310.1016/j.jcrysgro.2007.11.193 ↗
52. 10.1038/s41377-020-0281-410.1038/s41377-020-0281-4 ↗
53. 10.1007/s00340-004-1645-910.1007/s00340-004-1645-9 ↗
54. 10.1063/1.36806010.1063/1.368060 ↗
55. 10.1039/c3tc31872a10.1039/c3tc31872a ↗
56. 10.1063/1.46002510.1063/1.460025 ↗
57. 10.1107/s010876819001104110.1107/s0108768190011041 ↗
58. Brown I. D. · 2002
59. 10.1021/acs.jpcc.9b0876210.1021/acs.jpcc.9b08762 ↗