Poly(ionic liquid) Core Turns Hollow Silica Spheres into Amphiphilic Nanoreactor in Water
Source abstract
Abstract
The stressing environmental concerns push us to move traditional organic reactions toward an eco-friendly way. Replacing organic solvents by water seems to be a promising solution yet is very challenging. The main obstacle is the poor solubility of many hydrophobic substrates in water, leading to a restricted accessibility, thus inevitably ending up with low reaction rates. To overcome this problem, we propose a hybrid micelle-like hydrophobic@hydrophilic nanoreactor formed by a poly(ionic liquid) (PIL) core and a mesoporous silica shell. This nanoreactor exhibited high activity (TOF up to 414 h –1, 12.9 times of that for a corresponding silica catalyst) and selectivity (100%) in the oxidation of benzyl alcohol to benzaldehyde using water as solvent.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Mesoporous Materials and Catalysis · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Research Campus Golm, D-14476, Potsdam, Germany
Institute of Physics, Humboldt University of Berlin, D-12489, Berlin, Germany
Funding
Max-Planck-Gesellschaft
References (46)
Show source-provided references
1. Vriezema D. M. · Chem. Rev. · 2005 · 105 · 144510.1021/cr0300688 ↗
2. Peters R. J. R. W. · Chem. Sci. · 2012 · 3 · 33510.1039/C2SC00803C ↗
3. Ghosh Chaudhuri R. · Chem. Rev. · 2012 · 112 · 237310.1021/cr100449n ↗
4. Wu S. · Angew. Chem., Int. Ed. · 2012 · 51 · 222910.1002/anie.201106515 ↗
5. Yamada Y. · Nat. Chem. · 2011 · 3 · 37210.1038/nchem.1018 ↗
6. Jun S.-H. · Chem. Mater. · 2012 · 24 · 92410.1021/cm202125q ↗
7. Gligorich K. M. · Chem. Commun. · 2009 · 385410.1039/b902868d ↗
8. Yan N. · Coord. Chem. Rev. · 2010 · 254 · 117910.1016/j.ccr.2010.02.015 ↗
9. Uozumi Y. · Angew. Chem., Int. Ed. · 2003 · 42 · 19410.1002/anie.200390076 ↗
10. Crossley S. · Science · 2009 · 327 · 6810.1126/science.1180769 ↗
11. Yang H. Q. · Angew. Chem., Int. Ed. · 2013 · 52 · 745510.1002/anie.201300534 ↗
12. Wang Z. P. · Angew. Chem., Int. Ed. · 2012 · 51 · 1074610.1002/anie.201206555 ↗
13. Price K. E. · Chem. Commun. · 2005 · 171410.1039/b416892e ↗
14. Li J. · Green Chem. · 2008 · 10 · 60810.1039/b803209b ↗
15. Joo S. H. · Nat. Mater. · 2009 · 8 · 12610.1038/nmat2329 ↗
16. Beckers N. A. · ACS Catal. · 2012 · 2 · 152410.1021/cs3002447 ↗
17. Dehm N. A. · Inorg. Chem. · 2010 · 49 · 270610.1021/ic901928j ↗
18. Yang Y. · Angew. Chem., Int. Ed. · 2012 · 51 · 916410.1002/anie.201204829 ↗
19. Lee J. · Adv. Mater. · 2008 · 20 · 152310.1002/adma.200702338 ↗
20. Deng Y. H. · J. Am. Chem. Soc. · 2010 · 132 · 846610.1021/ja1025744 ↗
21. Yuan J. Y. · J. Am. Chem. Soc. · 2011 · 133 · 1755610.1021/ja207080j ↗
22. Green M. D. · Polym. Rev. · 2009 · 49 · 29110.1080/15583720903288914 ↗
23. Green O. · Polym. Rev. · 2009 · 49 · 33910.1080/15583720903291116 ↗
24. Mecerreyes D. · Prog. Polym. Sci. · 2011 · 36 · 162910.1016/j.progpolymsci.2011.05.007 ↗
25. Cui J. W. · Adv. Colloid Interface Sci. · 2014 · 207 · 1410.1016/j.cis.2013.10.012 ↗
26. Yuan J. Y. · Prog. Polym. Sci. · 2013 · 38 · 100910.1016/j.progpolymsci.2013.04.002 ↗
27. Lu J. · Prog. Polym. Sci. · 2009 · 34 · 43110.1016/j.progpolymsci.2008.12.001 ↗
28. Mecerreyes D. · Prog. Polym. Sci. · 2011 · 36 · 162910.1016/j.progpolymsci.2011.05.007 ↗
29. Texter J. · Macromol. Rapid Commun. · 2012 · 33 · 199610.1002/marc.201200525 ↗
30. Liao C. · New Carbon Mater. · 2014 · 29 · 7810.1016/S1872-5805(14)60127-X ↗
31. Yan F. · Angew. Chem., Int. Ed. · 2007 · 46 · 244010.1002/anie.200604127 ↗
32. Guntari S. N. · Adv. Funct. Mater. · 2013 · 23 · 515910.1002/adfm.201300768 ↗
33. Rozik N. · Macromol. Rapid Commun. · 2013 · 34 · 66510.1002/marc.201200827 ↗
34. Koebe M. · Macromol. Rapid Commun. · 2012 · 33 · 64610.1002/marc.201100836 ↗
35. Deng Y. H. · J. Am. Chem. Soc. · 2008 · 130 · 2810.1021/ja0777584 ↗
36. Soll S. · Small · 2013 · 9 · 413510.1002/smll.201300680 ↗
37. Bo X. J. · Biosens. Bioelectron. · 2011 · 28 · 7710.1016/j.bios.2011.07.001 ↗
38. Chun Y. S. · Chem. Commun. · 2008 · 94210.1039/B715463A ↗
39. Wu B. H. · Angew. Chem., Int. Ed. · 2009 · 48 · 475110.1002/anie.200900899 ↗
40. Prescher S. · J. Am. Chem. Soc. · 2014 · 136 · 1210.1021/ja409395y ↗
41. Lee J. S. · Chem. Mater. · 2009 · 21 · 475610.1021/cm902522b ↗
42. Kim B. H. · Chem. Mater. · 2013 · 26 · 5910.1021/cm402225z ↗
43. Yang H. Q. · Appl. Catal., A · 2010 · 382 · 31210.1016/j.apcata.2010.05.004 ↗
44. Jamwal N. · Green Chem. · 2008 · 10 · 99910.1039/b802135j ↗
45. Liu J. · Adv. Funct. Mater. · 2012 · 22 · 59110.1002/adfm.201101900 ↗
46. Ma C. Y. · Appl. Catal., B · 2009 · 92 · 20210.1016/j.apcatb.2009.07.007 ↗