Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers
Source abstract
Abstract
The mechanical adaptability of a family of six one-dimensional crystalline coordination polymers (CPs) of cadmium ([CdX2(3-X′py)2]n; 1: X = Br, X′ = Cl, 2: X = I, X′ = Cl, 3: X = I, X′ = Br, 4: X = Cl, X′ = I, 5: X = Br, X′ = I, and 6: X, X′ = I) to applied external force was examined, and a plethora of flexible responses was noticed. While two of the six CPs (4 and 6) were slightly elastic, the remaining four CPs (1–3 and 5) presented variable plastic deformation; three of these (1–3) displayed exceptional crystal flow, and one (2) demonstrated unprecedented ductility of crystalline metal–organic material. The feature was examined by theory and custom-designed experiments, and it was shown that specific and directional intermolecular interactions are not only the most influential structural feature in determining the type of mechanical responses (i.e., elastic vs plastic), with interlocking of adjacent molecules playing only a supportive role, but also an unavoidable tool for dialing-in a diversity of plastic responses in Cd(II) coordination polymers.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Crystallography and molecular interactions · Crystal structures of chemical compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia
Ruđer Bošković Institute, Bijenička c. 54, 10000 Zagreb, Croatia
Funding
European Regional Development Fund · Hrvatska Zaklada za Znanost
References (38)
Show source-provided references
1. 10.1002/anie.20180013710.1002/anie.201800137 ↗
2. 10.1038/s41467-019-11657-010.1038/s41467-019-11657-0 ↗
3. 10.1039/C7CE01915G10.1039/C7CE01915G ↗
4. 10.1039/C8CC00775F10.1039/C8CC00775F ↗
5. 10.1039/C8CS00406D10.1039/C8CS00406D ↗
6. 10.1002/anie.20190788910.1002/anie.201907889 ↗
7. Annadhasan M. · Synth. Met. · 2017 · 232 · 6010.1016/j.synthmet.2017.07.019 ↗
8. 10.1039/D0CS00475H10.1039/D0CS00475H ↗
9. 10.1002/anie.20180868710.1002/anie.201808687 ↗
10. Mei L. · Angew. Chem., Int. Ed. · 2020 · 59 · 1606110.1002/anie.202003808 ↗
11. 10.1021/acs.cgd.9b0099210.1021/acs.cgd.9b00992 ↗
12. 10.1002/anie.20191479810.1002/anie.201914798 ↗
13. Liu, X.; Michalchuk, A. A. L.; Bhattacharya, B.; Emmerling, F.; Pulham, C. R. Reversibilty in a Plastically Flexible Coordination Polymer Crystal: A High-Pressure Study. chemrxiv.org, submitted: September 29, 2020, URL: https://doi.org/10.26434/chemrxiv.13022606 (accessed: 2021-02-10)10.26434/chemrxiv.13022606 ↗
14. 10.1107/S205252061600395410.1107/S2052520616003954 ↗
15. 10.1039/b314522k10.1039/b314522k ↗
16. Bravais, A Etudes Crystallographiques; Gauthier-Villars: Paris, 1866, p 194–264.
17. Freidel G. · Bull. Soc. Fr. Mineral. · 1907 · 30 · 326
18. Donnay J. D. H. · Am. Mineral. · 1937 · 22 · 463
19. 10.1002/anie.20200106010.1002/anie.202001060 ↗
20. Timoshenko, S. Strength of materials Part 1; D. Van Nostrand Company: New York, 1940, p 88–127.
21. 10.1155/2019/170373910.1155/2019/1703739 ↗
22. 10.1016/S0924-0136(02)00316-310.1016/S0924-0136(02)00316-3 ↗
23. 10.1016/0749-6419(91)90035-W10.1016/0749-6419(91)90035-W ↗
24. Hertzberg, R. W.; Vinvi, R. P.; Hertzberg, J. L. Deformation and Fracture Mechanics of Engineering Materials; J. Wiley & Sons, 5th Ed. 2013, p 63–142.
25. 10.1002/anie.20181438710.1002/anie.201814387 ↗
26. 10.1088/0370-1298/64/9/11110.1088/0370-1298/64/9/111 ↗
27. Hameed, S.; Pelc, D.; Anderson, Z. W.; Klein, A.; Spieker, R. J.; Lukas, M.; Liu, Y.; Krongstad, M. J.; Osborn, R.; Leighton, C.; Fernandes, R. M.; Greven, M. Enhanced Superconductivity in Plastically Deformed Strontium Titanate. arXiv.org, submitted: May 1, 2020, URL: arxiv.org/abs/2005.00514 (accessed 2021-02-10)
28. 10.1021/ja953281x10.1021/ja953281x ↗
29. 10.1039/a906512a10.1039/a906512a ↗
30. 10.1021/acs.cgd.9b0128110.1021/acs.cgd.9b01281 ↗
31. 10.1038/nchem.212310.1038/nchem.2123 ↗
32. CrysAlisPRO, Oxford Diffraction/Agilent Technologies UK Ltd, Yarnton, England.
33. 10.1107/S205327331402637010.1107/S2053273314026370 ↗
34. 10.1107/S010876730704393010.1107/S0108767307043930 ↗
35. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams-Young, D.; Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J. Gaussian 16, Revision C.01, Gaussian, Inc.: Wallingford CT, 2016.
36. 10.1007/s00894-017-3212-410.1007/s00894-017-3212-4 ↗
37. 10.1080/0026897700010156110.1080/00268977000101561 ↗
38. 10.1063/1.47290210.1063/1.472902 ↗