journal article·2016-05-24Open access

Development of a High-Performance Donor–Acceptor Conjugated Polymer: Synergy in Materials and Device Optimization

Mei Gao, Jegadesan Subbiah, Paul B. Geraghty, Ming Chen, Balaji Purushothaman, Xiwen Chen, Tianshi Qin, Doojin Vak, Fiona H. Scholes, Scott E. Watkins, Melissa Skidmore, Gerard J. Wilson, Andrew B. Holmes, David J. Jones, Wallace W. H. Wong

Chemistry of Materials· Volume 28· Issue 10

Abstract

The development of a high-performance polymer PBDT-BT for bulk heterojunction solar cell devices is summarized. The polymer was first synthesized by Stille polycondensation, and solar cell devices in conventional geometry were optimized through the use of a lithium salt cathode interlayer reaching 6% power conversion efficiency. Improvements were made to the synthesis of the polymer using Suzuki polycondensation giving high-molecular-weight material in the M n = 100 kg/mol range. Further device optimization in inverted geometry gave power conversion efficiency of over 9%. The synthesis scalability as well as the batch-to-batch reproducibility of the polymer were extensively investigated.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CSIRO Manufacturing Flagship, Bag 10, Clayton South, Victoria 3169, Australia

School of Chemistry, Bio21 Institute, University of Melbourne, 30 Flemington Road, Melbourne, Victoria 3010, Australia

Funding

Australian Research Council · Commonwealth Scientific and Industrial Research Organisation · State Government of Victoria · Australian Renewable Energy Agency, Australian Government · Victorian Organic Solar Cell Consortium

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