Mechanisms of Quick Zeolite Beta Crystallization
Source abstract
Abstract
Silicate self-assembly and zeolite beta crystallization in the presence of 4,4′-trimethylenebis(N-methyl, N-benzyl piperidinium) (TMP 2+ ) structure directing agent were studied using a combination of 29 Si and 27 Al nuclear magnetic resonance (NMR), small angle scattering (SAS), and attenuated total reflectance Fourier transform infrared (ATR/FTIR) spectroscopy. Crystallization of nanosized siliceous TMP 2+ zeolite beta proceeds along three populations of particles (i.e., primary, secondary, and tertiary), differing in size and internal structure similar to crystallization of aluminum containing zeolite beta with tetraethylammonium (TEA + ) as structure directing agent. Aluminosilicate TMP 2+ zeolite beta, however, crystallizes along a very unique pathway, wherein secondary particles are final partially crystalline colloidally stable zeolite beta. TMP 2+ zeolite beta crystallizes quickly when compared to TEA + zeolite beta, which takes nearly a hundred hours to crystallize under similar synthesis conditions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Zeolite Catalysis and Synthesis · Chemical Synthesis and Characterization · Mesoporous Materials and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States
Tectospin, Institut Lavoisier de Versailles, University of Versailles Saint Quentin en Yvelines, France
Catalysis Center for Energy Innovation, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States
References (86)
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