Spontaneous Chiral Induction in a Cubic Phase
Source abstract
Abstract
The optical property and the molecular packing structure of achiral bent-rod-shaped liquid crystalline compound 1 possessing an amide group and a flexible spacer were investigated by polarized optical microscopy (POM), circular dichroism (CD) spectroscopy, and X-ray diffraction (XRD). The molecules generated highly ordered liquid crystal phases by lateral intermolecular hydrogen bonds. The cubic phase observed in this study showed a chirality in CD spectroscopy even without the aid of a dopant. Further, its chirality was enhanced by doping with chiral dopant compound 4 . The origin of the spontaneous chiral induction was postulated, and the packing structure in the aggregates was proposed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Liquid Crystal Research Advancements · Molecular spectroscopy and chirality · Surfactants and Colloidal Systems
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Quality Materials Science, Graduate School of Science and Technology, and Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
References (54)
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