Silicone/Amine Resin Hybrid Materials as Abrasion Resistant Coatings
Source abstract
Abstract
Hydroxyl organofunctional silicone solutions were prepared by acid-catalyzed hydrolysis and condensation of tetraalkoxysilanes, alkoxysilane modified organic compounds, and hydroxyl functional trialkoxysilanes or epoxy functional silanes. These silicone solutions were mixed with methoxylated urea formaldehyde and methoxylated melamine formaldehyde to form silicone/amine resin hybrids and applied on bisphenol A polycarbonate substrates as coatings. After thermal curing at 100−125 °C for 2−3 h, several optically transparent hard coatings with excellent abrasion resistance were obtained.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Silicone and Siloxane Chemistry · Synthesis and properties of polymers · Photopolymerization techniques and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Polymer Materials and Interfaces Laboratory, Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061
References (20)
Show source-provided references
1. Mackenzie J. · 1984 · 26
2. Schmidt, H.; Seiferling, B.; Philipp, G.; Deichmann, K. InUltrastructure Processing of Advanced Ceramics; Mackenzie, J. D., Ulrich, D. R., Eds.; John Wiley & Sons: New York, 1988; pp 651−660.
3. Wen J. · Chem. Mater · 1996 · 8 · 1681
4. Clark · Patent · 1976 · 3 · 986
5. Clark · Patent · 1977 · 4 · 027
6. Ubersax · Patent · 1979 · 4 · 177
7. Frye · Patent · 1981 · 4 · 277
8. Wang B. · Patent · 1994 · 5 · 316
9. Kasemann R. · New J. Chem · 1994 · 18 · 1123
10. Kasemann R. · Patent · 1999 · 6 · 008
11. Havey J. L. · Patent · 1999 · 6 · 001
12. Wilkes G. L. · Patent · 2000 · 6 · 072
13. Li C. · Wear · 2000 · 242 · 139
14. Updegraff, I. H.; Moore, S. T.; Herbes, W. F.; Roth, P. B. InKirk-Othmer Encyclopedia of Chemical Technology; Grayson, M., Eckroth, D., Mark, H., Othmer, D. F., Overberger, C. G., Seaborg, G. T., Eds.; John Wiley & Sons: New York, 1978; Vol. 2, pp 440−469.
15. Paul, S.Surface Coatings, Science and Technology; John Wiley & Sons: New York, 1985; pp 167−199.
16. Hill W. L. · J. Coatings Technol · 1999 · 71 · 134
17. Diaz I. · J. Modern Paint and Coatings · 1988 · 88 · 45
18. Brinker, C. J.; Scherer, G. W.Sol−Gel Science: The Physics andChemistry of Sol−Gel Processing; Academy Press: Boston, MA, 1990, (a) pp 213-215, (b) pp 802−819.
19. Resimene®High Solids Amino Resin Recommendation with Nacure& K−Cure Acid Catalysts; Technical Bulletin, Pub No. 2029261A, Solutia Inc., St. Louis, MO, URL: http:\\www.coatings-solutia.com\index.html.
20. Maprenal®& Resimene®; Technical Bulletin, Pub No. 2029665, Solutia Inc., St. Louis, MO, URL: http:\\www.coatings-solutia. com\index.html.