journal article·2020-01-14Open access

Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Amandine Cadiau, Lilia S. Xie, Nikita Kolobov, Aleksander Shkurenko, Muhammad Qureshi, Mohamed R. Tchalala, Sarah S. Park, Anastasiya Bavykina, Mohamed Eddaoudi, Mircea Dincă, Christopher H. Hendon, Jorge Gascon

Chemistry of Materials· Volume 32· Issue 1

Abstract

Nowadays, zirconium metal–organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV–vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Machine Learning in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States

Materials Science Institute, Department of Chemistry and Biochemistry, University of Oregon, Eugene, Oregon 97403, United States

Funding

Agence Nationale de la Recherche · Basic Energy Sciences · Division of Graduate Education

References (60)

Show source-provided references
1. 10.1016/j.mattod.2017.07.00610.1016/j.mattod.2017.07.006 ↗
2. 10.1021/jacs.6b0526110.1021/jacs.6b05261 ↗
3. 10.1021/acs.chemmater.5b0453810.1021/acs.chemmater.5b04538 ↗
4. 10.1021/ja054668v10.1021/ja054668v ↗
5. 10.1126/science.aaf632310.1126/science.aaf6323 ↗
6. 10.1039/c7cs00153c10.1039/c7cs00153c ↗
7. 10.1126/science.aam831010.1126/science.aam8310 ↗
8. 10.1039/c7cs00033b10.1039/c7cs00033b ↗
9. 10.1016/j.ccr.2019.03.00510.1016/j.ccr.2019.03.005 ↗
10. 10.1016/j.ccr.2018.11.00910.1016/j.ccr.2018.11.009 ↗
11. 10.1016/j.ccr.2018.08.01010.1016/j.ccr.2018.08.010 ↗
12. 10.1039/c7cs00122c10.1039/c7cs00122c ↗
13. 10.1002/anie.20141185410.1002/anie.201411854 ↗
14. 10.1021/jacs.5b0960010.1021/jacs.5b09600 ↗
15. 10.1016/j.ccr.2017.09.00110.1016/j.ccr.2017.09.001 ↗
16. 10.1039/c6cc00805d10.1039/c6cc00805d ↗
17. 10.1038/s41467-017-02256-y10.1038/s41467-017-02256-y ↗
18. 10.1002/ijch.20180007810.1002/ijch.201800078 ↗
19. 10.1002/anie.20150621910.1002/anie.201506219 ↗
20. 10.1039/c8cc02871k10.1039/c8cc02871k ↗
21. 10.1021/ja805795310.1021/ja8057953 ↗
22. 10.1021/cm102601v10.1021/cm102601v ↗
23. 10.1039/c8ce00455b10.1039/c8ce00455b ↗
24. 10.1016/j.ccr.2019.01.01710.1016/j.ccr.2019.01.017 ↗
25. 10.1039/c5cs00837a10.1039/c5cs00837a ↗
26. 10.1039/c8sc00961a10.1039/c8sc00961a ↗
27. 10.1021/jacs.8b0060510.1021/jacs.8b00605 ↗
28. 10.1039/b818607n10.1039/b818607n ↗
29. 10.1016/j.ccr.2008.09.01210.1016/j.ccr.2008.09.012 ↗
30. 10.1021/ic100546r10.1021/ic100546r ↗
31. 10.1016/j.ccr.2016.10.01110.1016/j.ccr.2016.10.011 ↗
32. 10.1002/anie.20161182410.1002/anie.201611824 ↗
33. 10.1021/jacs.8b0589010.1021/jacs.8b05890 ↗
34. 10.1039/c7sc04829g10.1039/c7sc04829g ↗
35. 10.1002/ijch.20180006810.1002/ijch.201800068 ↗
36. 10.1021/ja305982710.1021/ja3059827 ↗
37. 10.1021/jacs.6b0934510.1021/jacs.6b09345 ↗
38. 10.1021/jacs.6b1317610.1021/jacs.6b13176 ↗
39. 10.1039/C9SC03348C10.1039/C9SC03348C ↗
40. 10.1021/ja512437u10.1021/ja512437u ↗
41. 10.1039/c8sc04138e10.1039/c8sc04138e ↗
42. 10.1021/jacs.8b0912010.1021/jacs.8b09120 ↗
43. 10.1021/jacs.7b0218610.1021/jacs.7b02186 ↗
44. 10.1021/acscatal.6b0292310.1021/acscatal.6b02923 ↗
45. 10.1038/s41467-018-04152-510.1038/s41467-018-04152-5 ↗
46. 10.1021/ja510525s10.1021/ja510525s ↗
47. 10.1039/c8sc04220a10.1039/c8sc04220a ↗
48. Bruker. APEX2, Version 2014.11-0; Bruker AXS Inc.: Madison, Wisconsin, USA, 2014.
49. Bruker. SAINT, Version V8.34A; Bruker AXS Inc.: Madison, Wisconsin, USA, 2014.
50. Sheldrick, G. M. SADABS, Version 2014/5; Bruker AXS Inc.: Madison, Wisconsin, USA, 2008.
51. Sheldrick, G. M. XPREP, Version 2008/2; Brucker AXS Inc.: Madison, Wisconsin, USA, 2008.
52. 10.1107/s205322961402421810.1107/s2053229614024218 ↗
53. 10.1107/s002188981202911110.1107/s0021889812029111 ↗
54. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
55. 10.1103/physrevlett.100.13640610.1103/physrevlett.100.136406 ↗
56. 10.1063/1.240466310.1063/1.2404663 ↗
57. 10.1021/ja411007310.1021/ja4110073 ↗
58. 10.1021/acs.chemmater.7b0332010.1021/acs.chemmater.7b03320 ↗
59. 10.1021/jacs.5b0295610.1021/jacs.5b02956 ↗
60. 10.1038/srep2367610.1038/srep23676 ↗