Creating Giant Secondary Building Layers via Alkali-Etching Exfoliation for Precise Synthesis of Metal–Organic Frameworks
Source abstract
Abstract
Because of the disparity in dative bond strength, three-dimensional (3D) bulky metal–organic frameworks (MOFs) based on the azolate layers and carboxylate pillars can be exfoliated into ultrathin two-dimensional (2D) nanosheets via alkali-etching exfoliation method. The obtained MOFs nanosheets, as giant secondary building layers (SBLs), can assemble with different linkers to form a series of 3D MOFs, thus facilely incorporating diverse functional groups into structures. The strategy reported here presents a low-cost, convenient, and high-throughput method to prepare ultrathin 2D nanosheets not only for potential applications but also for the generation of giant SBLs for rational MOF construction.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Dendrimers and Hyperbranched Polymers
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Structural Chemistry, Fujian Institute of Innovation, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China
University of the Chinese Academy of Sciences, Beijing 100049, China
School of Life Sciences, Tsinghua University, Beijing 100084, P.R. China
Funding
Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Sciences
References (41)
Show source-provided references
1. 10.1021/acs.accounts.6b0057710.1021/acs.accounts.6b00577 ↗
2. 10.1021/acs.accounts.5b0053010.1021/acs.accounts.5b00530 ↗
3. 10.1039/C3CS60483G10.1039/C3CS60483G ↗
4. 10.1039/C6SC04357G10.1039/C6SC04357G ↗
5. 10.1021/acssuschemeng.9b0168510.1021/acssuschemeng.9b01685 ↗
6. 10.1039/b817735j10.1039/b817735j ↗
7. 10.1021/ar000034b10.1021/ar000034b ↗
8. 10.1021/ja511131710.1021/ja5111317 ↗
9. 10.1002/anie.20120604210.1002/anie.201206042 ↗
10. 10.1039/C5CC06162H10.1039/C5CC06162H ↗
11. 10.1039/C4CS00067F10.1039/C4CS00067F ↗
12. 10.1021/acs.chemmater.6b0262610.1021/acs.chemmater.6b02626 ↗
13. 10.1002/anie.20170235710.1002/anie.201702357 ↗
14. 10.1039/C4TA07115H10.1039/C4TA07115H ↗
15. 10.1039/C8CS00268A10.1039/C8CS00268A ↗
16. 10.1002/adma.20150364810.1002/adma.201503648 ↗
17. 10.1002/adma.20160010810.1002/adma.201600108 ↗
18. 10.1126/science.125422710.1126/science.1254227 ↗
19. 10.1002/advs.20180102910.1002/advs.201801029 ↗
20. 10.1002/smtd.20160003010.1002/smtd.201600030 ↗
21. 10.1002/adma.20170430310.1002/adma.201704303 ↗
22. 10.1073/pnas.060243910310.1073/pnas.0602439103 ↗
23. 10.1002/anie.20140767610.1002/anie.201407676 ↗
24. 10.1038/nchem.237410.1038/nchem.2374 ↗
25. 10.1038/nchem.222210.1038/nchem.2222 ↗
26. 10.1039/C4DT02961E10.1039/C4DT02961E ↗
27. 10.1021/ic702085x10.1021/ic702085x ↗
28. 10.1021/jacs.7b1306910.1021/jacs.7b13069 ↗
29. 10.1021/jacs.7b0345010.1021/jacs.7b03450 ↗
30. 10.1016/j.jcis.2017.04.07010.1016/j.jcis.2017.04.070 ↗
31. Yu H.-S. · Nucl. Sci. Tech. · 2015 · 26 · 50102
32. 10.1021/jacs.7b0293610.1021/jacs.7b02936 ↗
33. 10.1021/jacs.8b1152510.1021/jacs.8b11525 ↗
34. 10.1038/nmat411310.1038/nmat4113 ↗
35. 10.1038/nenergy.2016.18410.1038/nenergy.2016.184 ↗
36. 10.1038/ncomms1446010.1038/ncomms14460 ↗
37. 10.1039/C6TA03065C10.1039/C6TA03065C ↗
38. 10.1039/C4TA01749H10.1039/C4TA01749H ↗
39. 10.1071/CH1466910.1071/CH14669 ↗
40. 10.1021/cg500121f10.1021/cg500121f ↗
41. 10.1080/00958972.2013.86702310.1080/00958972.2013.867023 ↗