journal article·2013-02-26

Atomic Structure and Composition of “Pt3Co” Nanocatalysts in Fuel Cells: An Aberration-Corrected STEM HAADF Study

Brian Patrick, Hyung Chul Ham, Yang Shao-Horn, Lawrence F. Allard, Gyeong S. Hwang, Paulo J. Ferreira

Chemistry of Materials· Volume 25· Issue 4
Publisher page

Abstract

Pt 3 Co nanoparticles are used to promote the oxygen reduction kinetics and increase the efficiency of proton exchange membrane (PEM) fuel cells. For the first time, aberration-corrected scanning transmission electron microscopy (STEM), STEM image simulations, and DFT calculations are combined to provide insight into the origin of enhanced catalysis of Pt 3 Co nanoparticles. Acid-leached nanoparticles exhibit a solid-solution structure but heterogeneous composition, while heat-treated nanoparticles exhibit an ordered structure, except for the first three surface layers where Pt enrichment is observed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Machine Learning in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

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