K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions
Source abstract
Abstract
A new alkali metal iodate, K2Na(IO3)2(I3O8), has been synthesized using the mild hydrothermal method, which is the first example of noncentrosymmetric iodate containing isolated [IO3]− and [I3O8]− groups. To the best of our knowledge, it exhibits the largest second harmonic generation response among the iodates with two types of isolated I–O groups (7.6 × KH2PO4 (KDP) @1064 nm). It also possesses a moderate birefringence (Δn) of 0.055 at 1064 nm for achieving its phase matching and a wide band gap (3.83 eV) for obtaining a high laser damage threshold, which assures that it possesses a high laser-induced damage threshold (LDT, 13 × AgGaS2). These results indicate that it is a good candidate for nonlinear optical applications.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Crystal Structures and Properties · Solid State Laser Technologies · Photorefractive and Nonlinear Optics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, CAS, 40-1 South Beijing Road, Urumqi 830011, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Funding
Natural Science Foundation of Xinjiang Province · Youth Innovation Promotion Association of the Chinese Academy of Sciences · National Natural Science Foundation of China · Tianshan Innovation Team Program · Fujian Innovation Academy, Chinese Academy of Sciences
References (79)
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