Nanoporous Polymers from Cross-Linked Polymer Precursors viatert-Butyl Group Deprotection and Their Carbon Dioxide Capture Properties
Source abstract
Abstract
A two-step synthetic strategy has been developed to achieve functionalized nanoporous polymers via the deprotection of the cross-linked polymer precursors containing tert -butyl carboxylate-functionalized stilbene or styrene and N -phenylmaleimide alternating sequences. Three different deprotection methods to generate nanoporosity were examined in this work. The resulting nanoporous polymers showed a significant increase in BET surface area. The effects of cross-linking density and the stiffness of the alternating sequences on the nanoporosity of these polymers were studied. The resulting nanoporous polymers were also investigated as potential CO 2 sorbents.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Macromolecules and Interfaces Institute, Virginia Tech, Blacksburg, Virginia 24061-0344, United States
The Molecular Foundry, E.O. Lawrence Berkeley National Laboratory, Mailstop 67R6110, Berkeley, California 94720-8139, United States
Funding
Department of Chemistry, Virginia Polytechnic Institute and State University · Basic Energy Sciences · Division of Materials Research
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