journal article·2009-02-10

Direct Covalent Grafting of Polyoxometalates onto Si Surfaces

Meng Lu, Whitney M. Nolte, Tao He, David A. Corley, James M. Tour

Chemistry of Materials· Volume 21· Issue 3
Publisher page

Abstract

A diazonium salt-derived organoimido hexamolybdate was synthesized and directly covalently immobilized on Si surfaces using diazonium chemistry to form both monolayers and multilayers. These monolayers and multilayers were characterized by ellipsometry, X-ray photoelectron spectroscopy (XPS), and electrochemical analysis. The results of electrochemical analysis have shown a strong electronic interaction between the surface-confined clusters and the Si substrate through the organic conjugated bridge.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Polyoxometalates: Synthesis and Applications · Conducting polymers and applications · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Department of Mechanical Engineering and Materials Science, and The Smalley Institute for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005

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