journal article·2009-08-11

Mössbauer Spectroscopy and Magnetic Measurements As Complementary Techniques for the Phase Analysis of FeP Electrodes Cycling in Li-Ion Batteries

S. Boyanov, M. Womes, L. Monconduit, D. Zitoun

Chemistry of Materials· Volume 21· Issue 15
Publisher page

Abstract

Iron phosphide (FeP) anodes react with lithium through a conversion reaction FeP + 3Li = Li 3 P + Fe°, leading to nanosized Fe° particles embedded in a Li 3 P matrix. Electrochemical tests coupled to 57 Fe Mössbauer spectroscopy and magnetic measurements confirm the previously proposed reaction mechanism and complete the investigation of the electrodes by gaining information on the Fe nanoparticles size and surface state from magnetic measurements. More importantly, combining Mössbauer spectroscopy and magnetic measurements appears to be a powerful tool to characterize electrode materials and to give better insights into the complex lithiation−delithiation processes.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Magnetic Properties and Synthesis of Ferrites · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institut Charles Gerhardt, AIME, Université Montpellier II, Place E. Bataillon, 34095 Montpellier, France

Department of Chemistry and Center for Nanomaterials of the Institute for Nanotechnology, Bar Ilan University, Ramat Gan, Israel

References (34)

Show source-provided references
1. Bichat M. P. · J. Electrochem. Soc. · 2004 · 151 · A207410.1149/1.1815156 ↗
2. Souza D. C. S. · Science · 2002 · 296 · 201210.1126/science.1071079 ↗
3. Gillot F. · Electrochim. Acta · 2004 · 49 · 232510.1016/j.electacta.2004.01.013 ↗
4. Boyanov S. · Chem. Mater. · 2006 · 18 · 353110.1021/cm060433m ↗
5. Larcher D. · J. Electrochem. Soc. · 2006 · 153 · A177810.1149/1.2219711 ↗
6. Dedryvère R. · J. Power Sources · 2001 · 204 · 97
7. Chadwick A. V. · J. Phys. Chem. C · 2007 · 111 · 463610.1021/jp066417u ↗
8. Tamura N. · J. Electrochem. Soc. · 2006 · 153 · A162610.1149/1.2205156 ↗
9. Silva D. C. C. · Electrochem. Solid-State Lett. · 2003 · 6 · A16210.1149/1.1588112 ↗
10. Silva, D. C. C.Ph.D. Thesis,University of Waterloo,Waterloo, ON, 2006,
11. Franke W. · Z. Anorg. Allg. Chem. · 1934 · 218 · 34610.1002/zaac.19342180403 ↗
12. Juza R. · Z. Anorg. Allg. Chem. · 1968 · 361 · 5810.1002/zaac.19683610107 ↗
13. Kündig W. · Nucl. Instr. Methods Phys. Res. · 1969 · 75 · 33610.1016/0029-554X(69)90624-7 ↗
14. LeCaër G. · J. Phys. E · 1979 · 12 · 108310.1088/0022-3735/12/11/018 ↗
15. Pound R. V. · Phys. Rev. Lett. · 1960 · 4 · 27410.1103/PhysRevLett.4.274 ↗
16. Josephson B. D. · Phys. Rev. Lett. · 1960 · 4 · 34110.1103/PhysRevLett.4.341 ↗
17. Häggström L. · J. Magn. Magn. Mater. · 1982 · 30 · 24910.1016/0304-8853(82)90205-0 ↗
18. Felcher G. P. · Phys. Rev. B · 1971 · 3 · 304610.1103/PhysRevB.3.3046 ↗
19. Felcher G. P. · Phys. Rev. B · 1971 · 3 · 304610.1103/PhysRevB.3.3046 ↗
20. Wäppling R. · J. Solid State Chem. · 1971 · 3 · 27610.1016/0022-4596(71)90041-7 ↗
21. Hendriksen P. V. · Phys. Rev. B · 1993 · 48 · 725910.1103/PhysRevB.48.7259 ↗
22. Bodker F. · J. Magn. Magn. Mater. · 1995 · 373 · 140
23. Respaud M. · Phys. Rev. B · 1998 · 57 · 292510.1103/PhysRevB.57.2925 ↗
24. Wäppling R. · J. Solid State Chem. · 1975 · 13 · 25810.1016/0022-4596(75)90128-0 ↗
25. Bobadova-Parvanova P. · Phys. Rev. B · 2002 · 66 · 19540210.1103/PhysRevB.66.195402 ↗
26. Billas I. M. L. · Science · 1994 · 265 · 1662
27. Lacroix L. M. · J. Appl. Phys. · 2008 · 103
28. Pick S. · Phys. Rev. B · 1999 · 59 · 419510.1103/PhysRevB.59.4195 ↗
29. Rosensweig R. E. · AIAA J. · 1966 · 4 · 175110.2514/3.3773 ↗
30. Suslick K. S. · J. Am. Chem. Soc. · 1996 · 118 · 1196010.1021/ja961807n ↗
31. Park S.-J. · J. Am. Chem. Soc. · 2000 · 122 · 858110.1021/ja001628c ↗
32. Nikitenko S. I. · Angew. Chem., Int. Ed. · 2001 · 40 · 444710.1002/1521-3773(20011203)40:23<4447::AID-ANIE4447>3.0.CO;2-J ↗
33. Dumestre F. · Science · 2004 · 303 · 82110.1126/science.1092641 ↗
34. Kim D. · J. Am. Chem. Soc. · 2007 · 129 · 581210.1021/ja070667m ↗