Experimental reinvestigation of the CrSi-Si partial system and update of the thermodynamic description of the entire Cr-Si system
Source abstract
Abstract
The partial system CrSi-Si has been reinvestigated by differential thermal analysis (DTA) and x-ray diffraction (XRD) resulting in confirmation of the general features of the accepted phase diagram, but with significant corrections for most invariant reaction temperatures. Most prominently, the melting of CrSi2 has been found to occur at 1438 ‘ 2°C. Critical evaluation has reconciled the literature data with the present results. A new thermodynamic description of the entire Cr-Si system was derived using for input the present experimental results as well as previous model parameters. Within the experimental uncertainties, agreement is obtained between the experimentally determined and the modeled phase diagram as well as other thermodynamic functions.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · Semiconductor materials and interfaces · Metallurgical and Alloy Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. L.D. Dudkin and E.S. Kuznetsova: Sov. Powder Metall. Met. Ceram., 1962, vol. 12 (6), pp. 20–31.
2. L.B. Dubrovskaya and P.V. Gel’d: Russ. J. Inorg. Chem., 1963, vol. 8 (7), pp. 854–57.
3. V.N. Svechnikov, Y.A. Kocherzhinskii, and L.M. Yupko: Sb. Nauchn. Tr. Inst. Metallofiz., Akad. Nauk Ukr. SSR, 1964, vol. 19, pp. 212–18.
4. G.I. Kalishevich, P.V. Gel’d, and R.P. Krentsis: High Temp. (USSR), 1966, vol. 4 (5), pp. 613–18.
5. B.K. Voromov, L.D. Dudkin, N.I. Kiryuchina, and N.N. Trusova: Sov. Powder Metall. Met. Ceram., 1967, vol. 49 (1), pp. 56–61.10.1007/BF00773383 ↗
6. Y.A. Chang: Trans. TMS-AIME, 1968, vol. 242 (8), pp. 1509–15.
7. G.I. Kalishevich, P.V. Gel’d, and Y.V. Putintsev: Tr. Ural. Politekh. Inst., 1968, vol. 167, pp. 152–54.
8. V.N. Eremenko, G.M. Lukashenko, and V.R. Sidorko: Russ. J. Phys. Chem., 1971, vol. 45 (8), pp. 1133–34.
9. Y.A. Kocherzhinsky: Thermal Analysis, Vol. 1, Proc. Third ICTA Davos, Birkhäuser Verlag Basel, CH, 1971, pp. 549–59 (1971).
10. T.M. Pyatkova, V.I. Surikov, A.K. Shtol’ts, V.L. Zagryazhskii, and P.V. Gel’d: Izv. Akad. Nauk SSSR, Neorg. Mater., 1971, vol. 7 (10), pp. 1755–58.
11. V.N. Eremenko, G.M. Lukashenko, V.R. Sidorko, and A.M. Kharkova: Porosh. Met., 1972, vol. 12 (7), pp. 61–65.
12. J.-P. Riegert, A. Vermande, and I. Ansara: High Temp.-High Pressures, 1973, vol. 5, pp. 231–37.
13. T.G. Chart: Met. Sci., 1975, vol. 9, pp. 504–09.10.1179/030634575790445215 ↗
14. Y.O. Esin, P.V. Gel’d, Y.V. Gorbunov, V.I. Vasil’ev, and A.B. Galeznik: Russ. J. Phys. Chem., 1976, vol. 50 (10), pp. 1584–85.
15. M. Jurisch and G. Behr: Acta Phys. Acad. Sci. Hung., 1979, vol. 47 (1–3), pp. 201–07.10.1007/BF03156527 ↗
16. B. Sundman, B. Janssson, and J.-O. Andersson: CALPHAD, 1985, vol. 9 (2), pp. 153–90.10.1016/0364-5916(85)90021-5 ↗
17. G.M. Lukashenko, V.R. Sidorko, and L.M. Yupko: Porosh. Met., 1986, vol. 9, pp. 73–76.
18. C.E. Myers, G.A. Murray, R.J. Kematick, and M.A. Frisch: Proc. Electrochem. Soc., 1986, vol. 86 (2), pp. 47–58.
19. L. Topor and O.J. Kleppa: J. Chem. Thermodyn., 1987, vol. 19, pp. 69–75.10.1016/0021-9614(87)90164-9 ↗
20. W. Wacha: Master’s Thesis, Vienna Institute of Technology, Vienna, 1989.
21. T.B. Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak: Binary Alloy Phase Diagrams, ASM INTERNATIONAL, Materials Park, OH, 1990.
22. H.P. Thomas: Metrologia, 1990, vol. 27, pp. 3–10.10.1088/0026-1394/27/1/002 ↗
23. A.T. Dinsdale: CALPHAD, 1991, vol. 15 (4), pp. 317–425.10.1016/0364-5916(91)90030-N ↗
24. P. Villars and L.D. Calvert: Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM INTERNATIONAL, Materails Park, OH, 1991.
25. B.-J. Lee: CALPHAD, 1992, vol. 16 (2), pp. 121–49.10.1016/0364-5916(92)90002-F ↗
26. C.A. Coughanowr, I. Ansara, and H.L. Lukas: CALPHAD, 1994, vol. 18 (2), pp. 125–40.10.1016/0364-5916(94)90023-X ↗
27. J. Gröbner, H.L. Lukas, and F. Aldinger: CALPHAD, 1996, vol. 20 (2), pp. 247–54.10.1016/S0364-5916(96)00027-2 ↗
28. H.J. Seifert, H.L. Lukas, and G. Petzow: Z. Metallkd., 1996, vol. 87 (1), pp. 2–13.
29. Y. Du, R. Schmid-Fetzer, and H. Ohtani: Z. Metallkd., 1997, vol. 88 (7), pp. 545–56.
30. S.V. Meschel and O.J. Kleppa: J. Alloys Compounds, 1998, vol. 267, pp. 128–35.10.1016/S0925-8388(97)00528-8 ↗
31. H.J. Seifert: private communication, Max-Planck-Institut für Metallforschung, Stuttgart, Germany, 1998.
32. Y. Du, L. Perring, and J.C. Schuster: J. Am. Ceram. Soc., 2000, vol. 83, in print.10.1111/j.1151-2916.2000.tb01170.x ↗
33. Y. Du and J.C. Schuster: Scand. J. Metall., 2000, in review.
34. J.C. Schuster and Y. Du: Metall. Mater. Trans., 2000, vol. 31A, in print.10.1007/s11661-006-0248-y ↗
35. W.D. Zhuang, J.Y. Shen, Y.Q. Liu, L. Ling, S.L. Shang, Y. Du, and J.C. Schuster: Z. Metallkd., 2000, Vol. 91 (2), pp. 121–27.