The Phase Relationships in the Sb-S-I System and Thermodynamic Properties of the SbSI
Source abstract
Abstract
The phase relationships in the Sb-S-I ternary system were determined experimentally over entire concentration range by means of differential thermal analysis (DTA) and x-ray diffraction (XRD) techniques. Two quasi-binary, three isopleth sections, 300 K isothermal section and liquidus surface projection of the system were revised. The primary crystallization fields of all existing phases, the types and coordinates of all invariant and monovariant equilibria were determined. The electromotive force measurements (EMF) method was used to calculate the partial molar functions of antimony in alloys and the standard integral thermodynamic functions of SbSI.
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Research context
OpenAlex topics: Phase-change materials and chalcogenides · Solid-state spectroscopy and crystallography · Crystal Structures and Properties
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References (26)
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1. E.I. Gerzanich and V.M. Fridkin, Ferroelectric Materials of type A V B VI C VII , Nauka, Moscow, 1982
2. A. Pierrefeu, E.F. Steigmeier, and B. Dorner, Inelastic Neutron Scattering in SbSI, Near the Ferroelectric Phase Transformation, Phys. Status Solidi B, 1977, 80, p 167-17110.1002/pssb.2220800119 ↗
3. K. Žičkus, A. Audzijonis, J. Batarunas, and A. Šileika, The Fundamental Absorption Edge Tail of Ferroelectric SbSI, Phys. Status Solidi B, 1984, 125, p 645-65110.1002/pssb.2221250225 ↗
4. K.K. Rao and S.L. Chaplot, Dynamics of Paraelectric and Ferroelectric SbSI, Phys. Status Solidi B, 1985, 129, p 471-48210.1002/pssb.2221290204 ↗
5. J. Grigas, E. Talik, and V. Lazauskas, Splitting of the XPS in Ferroelectric SbSI, Crystals, Ferroelectrics, 2003, 284, p 147-16010.1080/00150190390204790 ↗
6. A. Audzijonis, R. Žaltauskas, L. Žigas, I.V. Vinokurova, O.V. Farberovich, A. Pauliukas, and A. Kvedaravičius, Variation of the Energy Gap of the SbSI, Crystals at Ferroelectric Phase Transition, Physica B, 2006, 371, p 68-7310.1016/j.physb.2005.09.039 ↗
7. A. Audzijonis, R. Sereika, and R. Žaltauskas, Antiferroelectric Phase Transition in SbSI, and SbSeI, Crystals, Solid State Commun., 2008, 147, p 88-8910.1016/j.ssc.2008.05.008 ↗
8. K. Łukaszewicz, A. Pietraszko, and M. Kucharska, Diffuse Scattering, Short Range Order and Nanodomains in the Paraelectric SbSI, Ferroelectrics, 2008, 375, p 170-17710.1080/00150190802438033 ↗
9. M. Nowak, A. Nowrot, P. Szperlich, M. Jesionek, M. Kępińska, A. Starczewska, K. Mistewicz, D. Stróż, J. Szala, T. Rzychoń, E. Talik, and R. Wrzalik, Fabrication and Characterization of SbSI, Gel for Humidity Sensors, Sens. Actuators A, 2014, 210, p 119-13010.1016/j.sna.2014.02.012 ↗
10. M.B. Babanly, J.C. Tedenac, Z.S. Aliev, and D.M. Balitsky, Phase Equilibriums and Thermodynamic Properties of the System Bi-Te-I, J. Alloys Compd., 2009, 481, p 349-35310.1016/j.jallcom.2009.02.139 ↗
11. Z.S. Aliev, S.S. Musaeva, D.M. Babanly, A.V. Shevelkov, and M.B. Babanly, Phase Diagram of the Sb-Se-I, System and Thermodynamic Properties of SbSeI, J. Alloys Compd., 2010, 505, p 450-45510.1016/j.jallcom.2010.06.103 ↗
12. Z.S. Aliev, D.M. Babanly, M.B. Babanly, A.V. Shevelkov, and I.R. Amiraslanov, Phase Diagram and Thermodynamic Properties of the System As-Te-I, J. Alloys Compd., 2011, 509, p 602-60810.1016/j.jallcom.2010.09.198 ↗
13. Z.S. Aliev, M.B. Babanly, D.M. Babanly, A.V. Shevelkov, and J.C. Tedenac, Phase Diagram of the Sb-Te-I, System and Thermodynamic Properties of SbTeI, Int. J. Mater. Res., 2012, 103, p 290-29510.3139/146.110646 ↗
14. Z.S. Aliev, Y.I. Jafarov, F.Y. Jafarli, A.V. Shevelkov, and M.B. Babanly, The Phase Equilibria in the Bi-S-I, Ternary System and Thermodynamic Properties of the BiSI, and Bi19S27I3 Ternary Compounds, J. Alloys Compd., 2014, 610, p 522-52810.1016/j.jallcom.2014.05.015 ↗
15. K. Ishizaka, M.S. Bahramy, H. Murakawa, M. Sakano, T. Shimojima, T. Sonobe, K. Koizumi, S. Shin, H. Miyahara, A. Kimura, K. Miyamoto, T. Okuda, H. Namatame, M. Taniguchi, R. Arita, N. Nagaosa, K. Kobayashi, Y. Murakami, R. Kumai, Y. Kaneko, Y. Onose, and Y. Tokura, Giant Rashba-Type Spin Splitting in Bulk BiTeI, Nat. Mater., 2011, 10, p 521-52610.1038/nmat3051 ↗
16. G. Landolt, S.V. Eremeev, Y.M. Koroteev, B. Slomski, S. Muff, T. Neupert, M. Kobayashi, V.N. Stroco, T. Schmitt, Z.S. Aliev, M.B. Babanly, I.R. Amiraslanov, E. Chulkov, J. Osterwalder, and J.H. Dil, Disentanglement of Surface and Bulk Rashba Spin Splittings in Noncentrosymmetric BiTeI, Phys. Rev. Lett., 2012, 109, p 11640310.1103/PhysRevLett.109.116403 ↗
17. L.M. Belyayev, V.A. Lyakhovitskaya, G.B. Netesov, M.V. Mokhosoev, and S.M. Aleykina, Synthesis and crystallization of antimony sulfoiodide, Izv. Akad. Nauk. Neorg. Mater., 1965, 1(12), p 2178-2181
18. T.A. Ryazantsev, L.M. Varekha, B.A. Popovkin, V.A. Lyakhovitskaya, and A.V. Novoselova, P-T-x phase diagram of the SbI3-Sb2S3, Izv. Akad. Nauk. Neorg. Mater., 1969, 5(7), p 2196-2197
19. K. Lukaszewicz, A. Pietraszko, Yu Stepen’ Damm, and A. Kajokas, Crystal Structure and Phase Transitions of the Ferroelectric Antimony Sulfoiodide Sb S I. Part II. Crystal Structure of SbSI, in Phases I, II, and III, Pol. J. Chem., 1997, 71, p 1852-1857
20. K. Itoh and H. Matsunaga, A Study of the Crystal Structure in Ferroelectric SbSI, Z. für Krist., 1980, 152, p 309-31510.1524/zkri.1980.152.3-4.309 ↗
21. T.B. Massalski, Binary Alloy Phase Diagrams, Vol 3, 2nd ed., ASM Inter. Mat. Park, Ohio, 1990
22. H. Okamoto, I-S (Iodine-Sulfur), J. Phase Equlib., 2000, 21, p 10910.1361/105497100770340516 ↗
23. M. Babanly, Y. Yusibov, and N. Babanly, The EMF Method with Solid-State Electrolyte in the Thermodynamic Investigation of Ternary Copper and Silver Chalcogenides, in Electromotive Force and Measurement in Several Systems, ed. by S. Kara (Intech, 2011), p 57-78 (ISBN 978-953-307-728-4)10.5772/28934 ↗
24. M. Babanly and Y. Yusibov, Electrochemical Methods in Thermodynamics of Inorganic Systems (Baku, 2011), p. 306 (ISBN 978-9952-453-17-1)
25. O. Kubaschewski, C.B. Alcock, and P.J. Spencer, Materials Thermochemistry, Pergamon Press, Oxford, 1993
26. V.S. Iorish and V.S. Yungman, Data Base of Thermal Constants of Substances. Digital version, 2006, http://www.chem.msu.ru/cgi-bin/tkv.pl