DataVXChemistry of MaterialsPaper
journal article·2017-01-24

Cooperative 1D Triazole-Based Spin Crossover FeII Material With Exceptional Mechanical Resilience

Narsimhulu Pittala, Franck Thétiot, Smail Triki, Kamel Boukheddaden, Guillaume Chastanet, Mathieu Marchivie

Chemistry of Materials· Volume 29· Issue 2
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Source abstract

Abstract

The magnetic spin change associated with the spin crossover (SCO) phenomenon represents a paradigm of bistability at the molecular level that is of current interest because of potential applications in the development of new generations of electronic devices such as nonvolatil memories, molecular sensors and displays.(1-5) The SCO phenomenon is especially observed in FeII complexes in which the paramagnetic high spin state (HS, S = 2) can be switched reversibly to the low spin state (LS, S = 0) by several external stimuli such as temperature, pressure or light irradiation.(6) A huge effort has been devoted to the understanding of the transition mechanisms using inter alia crystallographic tools...
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Magnetism in coordination complexes · Metal-Organic Frameworks: Synthesis and Applications · Metal complexes synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

UMR-CNRS 6521, University de Brest (UBO), 6 Avenue V. Le Gorgeu, C.S. 93837-29238 Brest Cedex 3, France

GEMaC, UMR-CNRS 8635, University de Paris-Saclay, 45 Avenue des Etats-Unis, 78035 Versailles, France

CNRS, University de Bordeaux, ICMCB, UPR 9048, 87 Avenue du Dr. A. Schweitzer, 33608 Pessac, France

Funding

Agence Nationale de la Recherche · Université de Bretagne Occidentale · Université Paris-Saclay · Université de Bordeaux · Centre National de la Recherche Scientifique · Directorate-General for Research and Innovation · Région Bretagne

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