journal article·2007-09-01

Mesoporous Silica: An Efficient Nanoreactor for Liquid−Liquid Biphase Reactions

Renyuan Zhang, Wei Ding, Bo Tu, Dongyuan Zhao

Chemistry of Materials· Volume 19· Issue 18
Publisher page

Abstract

Mesoporous silica can be used as a nanoreactor for liquid−liquid biphase reaction without any phase transfer reagent and organic cosolvent. High conversions (up to 89%) are achieved with low catalyst loading. This is attributed to the amphiphilic mesochannels, which can provide suitable accommodations for both hydrophilic and hydrophobic molecules.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Key Laboratory of Molecular Engineering of Polymers and Advanced Materials Laboratory, Fudan University, Shanghai 200433, People's Republic of China

References (21)

Show source-provided references
1. Kresge C. T. · Nature · 1992 · 359 · 71210.1038/359710a0 ↗
2. Zhao D. Y. · Science · 1998 · 279 · 552
3. Corma A. · Chem. Rev. · 1997 · 97 · 241910.1021/cr960406n ↗
4. Li C. · Catal. Rev. · 2004 · 46 · 492
5. Taguchi A. · Microporous Mesoporous Mater. · 2005 · 77 · 4510.1016/j.micromeso.2004.06.030 ↗
6. Zhao X. S. · Mater. Today · 2006 · 9 · 39
7. Wang Y. J. · Chem. Mater. · 2005 · 17 · 961
8. Liu C. J. · Chem. Commun. · 1997 · 65 · 66
9. Macquarrie D. · J. Chem. Commun. · 1996 · 1961 · 1962
10. Zhao X. S. · J. Phys. Chem. B · 1998 · 102 · 1561
11. Macquarrie D. J. · New J. Chem. · 1999 · 23 · 544
12. Bhaumik A. · J. Catal. · 2000 · 189 · 3910.1006/jcat.1999.2690 ↗
13. Pena M. L. · Microporous Mesoporous Mater. · 2001 · 44 · 356
14. Regen S. L. · J. Am. Chem. Soc. · 1975 · 97 · 595710.1021/ja00853a075 ↗
15. Balakrishnan T. · 1990
16. Wang M. L. · Ind. Eng. Chem. Res. · 2005 · 44 · 5426
17. Karimi B. · Org. Lett. · 2005 · 7 · 62810.1021/ol047635d ↗
18. Sato K. · J. Am. Chem. Soc. · 1997 · 119 · 12387
19. Noyori R. · Chem. Commun. · 2003 · 1977 · 1986
20. Cauvel A. · Langmuir · 1997 · 13 · 277810.1021/la962059i ↗
21. Feng K. · J. Am. Chem. Soc. · 2006 · 128 · 14690