journal article·2002-01-01

Characterization of a New Potassium Titanate, KTiO2(OH) Synthesized via Hydrothermal Method

Naruhiko Masaki, Satoshi Uchida, Hisanori Yamane, Tsugio Sato

Chemistry of Materials· Volume 14· Issue 1
Publisher page

Abstract

A new potassium titanate, KTiO 2 (OH), synthesized by hydrothermal oxidation of Ti metal powder in KOH solution was characterized. The X-ray photospectroscopy revealed that titanium contained in this compound consists of only Ti 4+, and FT-IR spectrum supported the existence of hydroxyl group in the structure. It was found that the titanate has a hexagonal tunnel structure with the space group P 6 1 22 and lattice parameters a = 9.8889 Å and c = 28.6711 Å, by crystal structure analysis with the use of powder XRD pattern. This agrees with the results of electron diffraction and morphology observed by SEM. The heating of KTiO 2 (OH) above 528 °C led to dehydration and phase transformation to give K 2 Ti 2 O 5 .
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Nuclear materials and radiation effects · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, Japan

References (39)

Show source-provided references
1. Marchand R. · Rev. Chim. Miner. · 1984 · 21 · 476
2. Sasaki T. · Inorg. Chem. · 1985 · 24 · 226510.1021/ic00208a028 ↗
3. Izawa H. · J. Solid State Chem. · 1985 · 60 · 26410.1016/0022-4596(85)90122-7 ↗
4. Izawa H. · J. Phys. Chem. · 1982 · 86 · 502310.1021/j100222a036 ↗
5. Sasaki T. · Chem. Mater. · 1992 · 4 · 89410.1021/cm00022a027 ↗
6. Fujiki Y. · Chem. Lett. · 1980 · 102310.1246/cl.1980.1023 ↗
7. Sasaki T. · Chem. Lett. · 1981 · 95710.1246/cl.1981.957 ↗
8. Behrens E. A. · Environ. Sci. Technol. · 1998 · 32 · 10110.1021/es9704794 ↗
9. Sasaki T. · Chem. Mater. · 1996 · 8 · 77710.1021/cm950463h ↗
10. Izawa H. · Polyhedron · 1983 · 2 · 74110.1016/S0277-5387(00)87201-0 ↗
11. Izawa H. · J. Solid State Chem. · 1987 · 69 · 33610.1016/0022-4596(87)90091-0 ↗
12. Miyata H. · J. Chem. Soc., Faraday Trans. 1 · 1988 · 84 · 267710.1039/f19888402677 ↗
13. Nakato T. · J. Phys. Chem. · 1995 · 99 · 1789610.1021/j100051a015 ↗
14. Cheng S. · Inorg. Chem. · 1989 · 28 · 128310.1021/ic00306a016 ↗
15. Kondo J. N. · J. Phys. Chem. · 1995 · 99 · 1604310.1021/j100043a051 ↗
16. Machida M. · Stud. Surf. Sci. Catal. · 1998 · 118 · 95
17. Kooli F. · Langmuir · 1999 · 15 · 109010.1021/la9809776 ↗
18. Machida M. · J. Mol. Catal. A: Chem. · 2000 · 155 · 13110.1016/S1381-1169(99)00329-5 ↗
19. Anderson S. · Acta Chem. Scand. · 1961 · 15 · 66310.3891/acta.chem.scand.15-0663 ↗
20. Verbaere A. · Bull. Soc. Chim. Fr. · 1973 · 4 · 1237
21. Kudo A. · J. Mater. Chem. · 1997 · 7 · 77710.1039/a606297k ↗
22. Shibata M. · Chem. Lett. · 1987 · 101710.1246/cl.1987.1017 ↗
23. Sato T. · J. Chem. Soc., Faraday Trans. · 1996 · 92 · 508910.1039/ft9969205089 ↗
24. Tsujikawa Y. · Gosei Jushi. · 1990 · 36 · 44
25. Halberstadt M. L. · Wear · 1978 · 46 · 10910.1016/0043-1648(78)90114-X ↗
26. Gulledge H. C. · Ind. Eng. Chem. · 1960 · 52 · 11710.1021/ie50602a022 ↗
27. Rau H. · Solid State Commun. · 1967 · 5 · 33110.1016/0038-1098(67)90767-3 ↗
28. Kniep R. · Top. Curr. Chem. · 1983 · 111 · 14510.1007/3-540-12065-3_3 ↗
29. Nishizawa H. · J. Am. Ceram. Soc. · 1982 · 65 · 34310.1111/j.1151-2916.1982.tb10467.x ↗
30. Masaki N. · J. Mater. Sci. · 2000 · 35 · 330710.1023/A:1004835724752 ↗
31. Uchida, S.; Masaki, N.; Yamane, H.; Sato, T.High-Pressure Res.2001,20, 71.10.1080/08957950108206154 ↗
32. Altmare A. · Mater. Sci. Forum · 1998 · 278 · 28410.4028/www.scientific.net/MSF.278-281.284 ↗
33. Izumi F. · Mater. Sci. Forum · 2000 · 321 · 19810.4028/www.scientific.net/MSF.321-324.198 ↗
34. Chastain J. · 1992
35. Lu G. · Surf. Sci. · 2000 · 458 · 8010.1016/S0039-6028(00)00420-9 ↗
36. Longo J. M. · J. Solid State Chem. · 1969 · 1 · 10310.1016/0022-4596(69)90015-2 ↗
37. Shono Y. · J. Phys. Soc. Jpn. · 1969 · 26 · 99310.1143/JPSJ.26.993 ↗
38. Hardy P. A. · Acta Crystallogr. · 1962 · 15 · 17910.1107/S0365110X6200047X ↗
39. Schmitz-DuMont O. · Monatsh. Chem. · 1959 · 90 · 13410.1007/BF00925227 ↗