journal article·2008-01-01

[Ni(1,2-PDA)3]2(HOCH2CH2CH2NH3)3(H3O)2 [Ge7O14X3]3 (X = F, OH): A New 1D Germanate with 12-Ring Hexagonal Tubular Channels

Qinhe Pan, Jiyang Li, Xiaoyan Ren, Zhuopeng Wang, Guanghua Li, Jihong Yu, Ruren Xu

Chemistry of Materials· Volume 20· Issue 2
Publisher page

Abstract

A novel one-dimensional germanate [Ni(1,2-PDA)3]2(HOCH2CH2CH2NH3)3 (H3O)2[Ge7O14X3]3 (X = F, OH) made of Ge7 clusters has been prepared with 12-ring hexagonal tubular channels. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol, which plays a dual role of SDA and solvent.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Polyoxometalates: Synthesis and Applications · Crystal Structures and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

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