journal article·2015-10-13

Low Temperature Synthesis and Surface Plasmon Resonance of Colloidal Lanthanum Hexaboride (LaB6) Nanocrystals

Tracy M. Mattox, Ankit Agrawal, Delia J. Milliron

Chemistry of Materials· Volume 27· Issue 19
Publisher page

Abstract

Lanthanum hexaboride (LaB 6 ) nanocrystals, with an ∼1000 nm wavelength localized surface plasmon resonance ideal for interacting with solar near-infrared radiation, have been synthesized for the first time in a relatively low temperature flask reaction using sodium borohydride as both boron source and “solvent”. Furthermore, the incorporation of isophthalic acid as a ligand allows the nanocrystals to disperse, permitting direct incorporation into polymer matrices including poly(methyl methacrylate) and polystyrene, suitable for composites and coatings.
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Research context

OpenAlex topics: Ion-surface interactions and analysis · Quantum Dots Synthesis And Properties · Rare-earth and actinide compounds

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Affiliations

The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, California 94720, United States

McKetta Department of Chemical Engineering, The University of Texas at Austin, 200 East Dean Keeton Street, Austin, Texas 78712, United States

Funding

Welch Foundation · Office of Science

References (36)

Show source-provided references
1. 10.1038/nmat302910.1038/nmat3029 ↗
2. 10.1002/mabi.20110043510.1002/mabi.201100435 ↗
3. 10.1038/nmat262910.1038/nmat2629 ↗
4. 10.1038/nature0193710.1038/nature01937 ↗
5. 10.1063/1.158409210.1063/1.1584092 ↗
6. 10.1557/jmr.2012.2510.1557/jmr.2012.25 ↗
7. 10.1038/nature1239810.1038/nature12398 ↗
8. 10.1063/1.192487310.1063/1.1924873 ↗
9. 10.1021/ja906441510.1021/ja9064415 ↗
10. 10.1021/cm060548q10.1021/cm060548q ↗
11. 10.1016/j.matchemphys.2004.03.01210.1016/j.matchemphys.2004.03.012 ↗
12. 10.1063/1.473338610.1063/1.4733386 ↗
13. 10.1021/acs.nanolett.5b0219710.1021/acs.nanolett.5b02197 ↗
14. 10.1021/ja401428e10.1021/ja401428e ↗
15. 10.1021/nn400894d10.1021/nn400894d ↗
16. 10.1021/acs.chemmater.5b0027010.1021/acs.chemmater.5b00270 ↗
17. 10.1016/j.ceramint.2011.03.07310.1016/j.ceramint.2011.03.073 ↗
18. 10.1063/1.169994610.1063/1.1699946 ↗
19. 10.1016/0022-0248(71)90173-410.1016/0022-0248(71)90173-4 ↗
20. 10.1016/0022-5088(68)90010-610.1016/0022-5088(68)90010-6 ↗
21. 10.1557/JMR.2010.007510.1557/JMR.2010.0075 ↗
22. 10.1016/j.ultramic.2011.05.00310.1016/j.ultramic.2011.05.003 ↗
23. 10.1016/j.jssc.2007.12.01110.1016/j.jssc.2007.12.011 ↗
24. 10.1021/cm702315x10.1021/cm702315x ↗
25. 10.1016/S0022-3697(97)00230-810.1016/S0022-3697(97)00230-8 ↗
26. 10.1021/ja043512c10.1021/ja043512c ↗
27. 10.1002/ejic.20080005310.1002/ejic.200800053 ↗
28. 10.1021/jp062091d10.1021/jp062091d ↗
29. 10.1002/jrs.125024040510.1002/jrs.1250240405 ↗
30. 10.1016/0022-2860(88)80200-X10.1016/0022-2860(88)80200-X ↗
31. 10.1006/jssc.2000.881610.1006/jssc.2000.8816 ↗
32. 10.1021/nn700360310.1021/nn7003603 ↗
33. 10.1021/jp984796o10.1021/jp984796o ↗
34. 10.1021/jp302732s10.1021/jp302732s ↗
35. 10.1021/am301481j10.1021/am301481j ↗
36. 10.1021/cr068028210.1021/cr0680282 ↗