Preparation, Transport Properties, and Structure Analysis by Resonant X-ray Scattering of the Type I Clathrate Cs8Cd4Sn42
Source abstract
Abstract
Structural and transport properties of Cs 8 Cd 4 Sn 42 are reported. Cs 8 Cd 4 Sn 42 has a thermal conductivity that is unusually low for a crystalline solid (1 W m - 1 K - 1 at room temperature). This low lattice thermal conductivity is associated with the rattling of cesium in the tetrakaidecahedral cavities, as indicated by the large atomic displacement parameters of Cs in the tretrakaidecahedra. Resonant X-ray powder diffraction measurements indicate that all of the cadmium is located on one of three inequivalent framework sites. There is no evidence for any framework vacancies in the material.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: X-ray Diffraction in Crystallography · Crystal Structures and Properties · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400; School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332-0430; SRI-CAT, Advanced Photon Source, Argonne National Laboratory, Illinois 60439-4803; and Department of Physics, University of South Florida, Tampa, Florida 33620-5700
References (44)
Show source-provided references
1. Cros C. · Acad. Sci. Paris · 1965 · 260 · 4767
2. Kasper J. S. · Science · 1965 · 150 · 171410.1126/science.150.3704.1713 ↗
3. Jeffrey G. · 1984 · 1 · 190
4. Eisenmann B. · J. Less-Common Met. · 1986 · 118 · 5510.1016/0022-5088(86)90609-0 ↗
5. Bobev S. · J. Solid State Chem. · 2000 · 153 · 10510.1006/jssc.2000.8755 ↗
6. Kawaji H. · Phys. Rev. Lett. · 1995 · 74 · 142910.1103/PhysRevLett.74.1427 ↗
7. Bryan J. D. · Phys. Rev. B · 1999 · 60 · 306710.1103/PhysRevB.60.3064 ↗
8. Adams G. B. · Phys. Rev. B · 1994 · 49 · 805310.1103/PhysRevB.49.8048 ↗
9. Keppens V. · Philos. Mag. Lett. · 2000 · 80 · 81210.1080/09500830010003830 ↗
10. Cohn J. L. · Phys. Rev. Lett. · 1999 · 82 · 782
11. Nolas G. S. · Appl. Phys. Lett. · 1998 · 73 · 18010.1063/1.121747 ↗
12. Nolas G. S. · Phys. Rev. B · 2000 · 61 · 384510.1103/PhysRevB.61.3845 ↗
13. Nolas, G. S.; Slack, G. A.; Schujman, S. B. InRecent Trends inThermoelectric Materials Research I; Tritt, T. M., Ed.; Academic Press: San Diego, 2001; Vol. 69, pp 255−300.10.1016/S0080-8784(01)80152-6 ↗
14. Kauzlarich S. M. · 1996
15. Nolas G. S. · Chem. Mater. · 1999 · 11 · 247310.1021/cm990164i ↗
16. Zhao J.-T. · Inorg. Chem. · 1994 · 33 · 5726
17. Nolas G. S. · Chem. Mater. · 2000 · 12 · 195310.1021/cm990686y ↗
18. Kroner R. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 672
19. von Schnering H. G. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 678
20. von Schnering H. G. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 674
21. Kroner R. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 670
22. von Schnering H. G. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 67910.1524/ncrs.1998.213.14.679 ↗
23. Kroner R. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 668
24. Kroner R. · Z. Kristallogr.New Cryst. Struct. · 1998 · 213 · 676
25. Chakoumakos B. C. · J. Alloys Compd. · 2000 · 296 · 8610.1016/S0925-8388(99)00531-9 ↗
26. Blake N. P. · J. Chem. Phys. · 1999 · 111 · 314410.1063/1.479615 ↗
27. Hodeau J.-L. · Chem. Rev. · 2001 · 101 · 1867
28. Cox, D. E.; Wilkinson, A. P. InResonant Anomalous X-rayScattering: Theory and Applications; Materlik, G., Sparks, C. J., Fischer, K., Eds.; North-Holland: Amsterdam, 1994; pp 195−219.
29. Warner J. K. · J. Phys. Chem. Solids · 1991 · 52 · 125610.1016/0022-3697(91)90200-J ↗
30. Cheetham A. K. · Angew. Chem., Int. Ed. Engl. · 1992 · 31 · 157010.1002/anie.199215571 ↗
31. Shastri, S. D.; Mashayekhi, A.; Fezzaa, K.; Lee, W.K.; Fernandez, P. B.; Tajiri, G. C.; Ferguson, D. A.; Lee, P. L.APS Activity Report; Argonne National Laboratory report ANL-00/5: 2001; Vol. 1, pp 258−259.
32. Rietveld H. M. · J. Appl. Crystallogr. · 1969 · 2 · 7110.1107/S0021889869006558 ↗
33. Larson A. C. · 1987
34. Cromer D. T. · J. Appl. Crystallogr. · 1983 · 16 · 43710.1107/S0021889883010791 ↗
35. Evans G. · J. Appl. Crystallogr. · 2000 · 34 · 86
36. Sales B. C. · J. Solid State Chem. · 1999 · 146 · 53210.1006/jssc.1999.8354 ↗
37. Sales, B. C.; Mandrus, D. G.; Chakoumakos, B. C. InRecent Trends inThermoelectric Materials Research II; Tritt, T. M., Eds.; Academic Press: San Diego, 2001; Vol. 70, pp 1−36.10.1016/S0080-8784(01)80135-6 ↗
38. Kittel C. · 1986
39. Sales B. C. · Phys. Rev. B · 2001 · 63 · 24511310.1103/PhysRevB.63.245113 ↗
40. Chakoumakos B. C. · J. Alloys Compd. · 2001 · 322 · 13410.1016/S0925-8388(01)01169-0 ↗
41. Emsley J. · 1991
42. Gimarc B. M. · J. Am. Chem. Soc. · 1983 · 105 · 198410.1021/ja00345a053 ↗
43. Miller G. · 1996 · 59
44. Latturner S. · J. Solid State Chem. · 2000 · 151 · 6410.1006/jssc.2000.8622 ↗