Electrochemical Synthesis of LiTiO2 and LiTi2O4 in Molten LiCl
Source abstract
Abstract
The rock salt-type LiTiO 2 and spinel-type LiTi 2 O 4 were synthesized with accurate control of stoichiometry by electrochemical insertion of Li + into solid TiO 2 (anatase) in molten LiCl. The behavior of Li + insertion was investigated by cyclic voltammetry using a “TiO 2 powder modified molybdenum electrode”. The results indicate two Li + insertion reactions at two different potentials for the formation of LiTiO 2 and LiTi 2 O 4, respectively, as confirmed by ICP, XRD, and TEM analyses.
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Research context
OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry and Molecular Science, and Centre for Electron Microscopy, Wuhan University, Wuhan, 430072, People's Republic of China, and School of Chemical, Environmental and Mining Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, U.K.
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