Thermodynamic and Structural Investigations of Ammonium Borohydride, a Solid with a Highest Content of Thermodynamically and Kinetically Accessible Hydrogen
Source abstract
Abstract
Ammonium borohydride releases >20 wt % hydrogen in three steps at temperatures <160 °C and provides evidence that [NH4]+[BH4]− crystallizes at room temperature and standard pressure in a rock salt [RS] structure and not a ZB structure that was previously proposed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Hydrogen Storage and Materials · Boron and Carbon Nanomaterials Research · Inorganic Fluorides and Related Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Pacific Northwest National Laboratory, Richland, Washington 99354
Chemistry, School of Engineering and Physical Sciences, Herriot Watt University, Edinburgh EH14 4AS, United Kingdom
References (23)
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23. ΔA=A(RS) −A(ZB) = ΔE−TΔS= 30.8−172.1 = −141.3 kcal for 32 pair cell.