Structural Study on Columnar Mesophases Consisting of H-Bonded Supramolecules

The use of complementary 2,4,6-triarylamino-1,3,5-triazines and benzoic acids has allowed the preparation of a variety of disklike supramolecules with different substitution patterns around an H-bonded aromatic core. Most of the complexes obtained show columnar mesomorphism promoted by an efficient columnar packing of the aromatic cores surrounded by a minimum of six peripheral tails. The steric requeriments for the appearance of mesomorphic behavior in these supramolecular complexes have been established by X-ray diffraction studies and density calculations based on the parameters of the liquid crystalline organization.