journal article·2000-03-01

CVD-Grown Thin Films of Molecule-Based Magnets

Dominique de Caro, Mario Basso-Bert, Jamal Sakah, Hélène Casellas, Jean-Pierre Legros, Lydie Valade, Patrick Cassoux

Chemistry of Materials· Volume 12· Issue 3
Publisher page

Abstract

Thin films of solvent-free molecule-based magnets [Cp*2Fe]•+[TCNE]•- and V(TCNE)x are grown by chemical vapor deposition on KBr pellets. [Cp*2Fe]•+[TCNE]•- films are crystalline and magnetically order at 3.7 K. Despite of their faceted grain morphology, V(TCNE)x films are amorphous. They exhibit field-dependent magnetization and hysteresis at room temperature.
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Research context

OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Porphyrin and Phthalocyanine Chemistry

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Affiliations

CNRS, UPR 8241, Laboratoire de Chimie de Coordination, Equipe “Précurseurs moléculaires et matériaux”, 205, route de Narbonne, F 31077 Toulouse Cedex 04 France

References (15)

Show source-provided references
1. Miller J. S. · J. Angew. Chem., Int. Ed. Engl. · 1994 · 33 · 415
2. (b) Cassoux, P.; Miller, J. S.Electron-transfer salt-based conductors,superconductors, and magnets; Interrante, L. V., Hampden-Smith, M. J., Eds.; Wiley-VCH: New York, 1998; pp 19−71.
3. Manriquez J. M. · Science · 1991 · 252 · 1710.1126/science.252.5011.1415 ↗
4. Ferlay S. · Nature · 1995 · 378 · 310.1038/378701a0 ↗
5. Létard J.-F. · J. Am. Chem. Soc. · 1997 · 119 · 2
6. Buschmann W. E. · Chem. Mater. · 1998 · 10 · 9510.1021/cm970773v ↗
7. Caro J. · Adv. Mater. · 1998 · 10 · 1010.1002/(SICI)1521-4095(199805)10:8<608::AID-ADMA608>3.0.CO;2-L ↗
8. Miller J. S. · J. Am. Chem. Soc. · 1987 · 109 · 81
9. Miller J. S. · J. Chem. Commun. · 1998 · 1319 · 25
10. Calderazzo F. · J. Organomet. Chem. · 1993 · 451 · 81
11. Figueras A. · J. Cryst. Growth · 1996 · 166 · 80310.1016/0022-0248(96)00075-9 ↗
12. Chaudari P. · Appl. Phys. Lett. · 1974 · 24 · 4210.1063/1.1655002 ↗
13. (a) Zhou, P.; Morin, B. G.; Miller, J. S.; Epstein, A. J.Phys. Rev. B: Condens.Matter1993,48, 1325−1328.10.1103/PhysRevB.48.1325 ↗
14. Zhou P. · J. Phys. Lett. A · 1993 · 181 · 910.1016/0375-9601(93)91127-Q ↗
15. Morin B. · J. Appl. Phys. · 1994 · 75 · 410.1063/1.355561 ↗