journal article·2014-04-22

Li-Anode Protective Layers for Li Rechargeable Batteries via Layer-by-Layer Approaches

Sun Hwa Lee, Jonathon R. Harding, David S. Liu, Julio M. D’Arcy, Yang Shao-Horn, Paula T. Hammond

Chemistry of Materials· Volume 26· Issue 8
Publisher page

Abstract

Li–anode protective layers were fabricated using layer-by-layer (LBL) assembly. The simple deposition on a polymer support membrane of an ionic conductive polymer and graphene oxide (GO) resulted in high ionic conductivity, controlled electrolyte permeability, and high-Li-transfer number. The uniformly coated LbL protective layer suppressed Li dendritic growth on the Li surface and improved Li electrode cyclability. This makes it possible to use Li metal for rechargeable Li batteries.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States

Department of Mechanical Engineering, Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States

References (27)

Show source-provided references
1. Richter B. · 2008
2. Bruce P. G. · Nat. Mater. · 2012 · 11 · 1910.1038/nmat3191 ↗
3. Girishkumar G. · J. Phys. Chem. Lett. · 2010 · 1 · 219310.1021/jz1005384 ↗
4. Goodenough J. B. · Chem. Mater. · 2009 · 22 · 58710.1021/cm901452z ↗
5. Abraham K. · J. Electrochem. Soc. · 1996 · 143 · 110.1149/1.1836378 ↗
6. Winter M. · Adv. Mater. · 1998 · 10 · 72510.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z ↗
7. Aurbach D. · Solid State Ionics · 2002 · 148 · 40510.1016/S0167-2738(02)00080-2 ↗
8. Yamaki J. · J. Power Sources · 1998 · 74 · 21910.1016/S0378-7753(98)00067-6 ↗
9. Aurbach D. · Electrochim. Acta · 1994 · 39 · 5110.1016/0013-4686(94)85010-0 ↗
10. Aurbach D. · Electrochim. Acta · 1990 · 35 · 62510.1016/0013-4686(90)87055-7 ↗
11. Kominato A. · J. Power Sources · 1997 · 68 · 47110.1016/S0378-7753(97)02592-5 ↗
12. Odziemkowski M. · J. Electrochem. Soc. · 1992 · 139 · 305210.1149/1.2069032 ↗
13. Shin J. H. · J. Electrochem. Soc. · 2005 · 152 · A97810.1149/1.1890701 ↗
14. Zhang T. · J. Electrochem. Soc. · 2010 · 157 · A21410.1149/1.3271103 ↗
15. Zhang X. W. · J. Electrochem. Soc. · 2004 · 151 · A125710.1149/1.1767158 ↗
16. DeLongchamp D. M. · Langmuir · 2004 · 20 · 540310.1021/la049777m ↗
17. Sukhishvili S. A. · J. Am. Chem. Soc. · 2000 · 122 · 955010.1021/ja002410t ↗
18. Sukhishvili S. A. · Macromolecules · 2002 · 35 · 30110.1021/ma011346c ↗
19. Park S. · Chem. Mater. · 2008 · 20 · 659210.1021/cm801932u ↗
20. Lichtner P. C. · 1996 · 3410.1515/9781501509797 ↗
21. Evans J. · Polymer · 1987 · 28 · 232410.1016/0032-3861(87)90394-6 ↗
22. Bear J. · 1972
23. Uthaisar C. · Nano Lett. · 2010 · 10 · 283810.1021/nl100865a ↗
24. Yang X. · Adv. Funct. Mater. · 2013 · 23 · 335310.1002/adfm.201203556 ↗
25. Zhou X. · J. Mater. Chem. · 2011 · 21 · 335310.1039/c0jm03287e ↗
26. Dikin D. A. · Nature · 2007 · 448 · 45710.1038/nature06016 ↗
27. Tang Z. · Nat. Mater. · 2003 · 2 · 41310.1038/nmat906 ↗