journal article·2024-12Open access

On Hillert-Style Non-equilibrium Thermodynamics

John Ågren

Abstract

Abstract Hillert often used the combined first and second law of thermodynamics to discuss and derive the principles of equilibrium as well as non-equilibrium thermodynamics. His method will now be reviewed and applied to reactions in homogeneous systems as well as transport processes As an example of homogeneous systems undercooled liquids and glasses is discussed.
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Research context

OpenAlex topics: Advanced Thermodynamics and Statistical Mechanics · Phase Equilibria and Thermodynamics · Theoretical and Computational Physics

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References (9)

Show source-provided references
1. M. Hillert, Phase Equilibria, Phase Diagrams and Phase Transformations, Their Thermodynamic Basis. Cambridge: Cambridge University Press, 2008.
2. J.W. Gibbs, The Collected Works of J. Willard Gibbs, vol. 1. New York: Longman, Green and Co, 1928.
3. R. Haase, Thermodynamics of Irreversible Proccesses. New York: Addison-Wesley, 1969.
4. L. Onsager, Reciprocal Relations in Irreversible Processes. I. Phys. Rev. 1931, 37, p 405-426.10.1103/PhysRev.37.405 ↗
5. C. Truesdell, Rational Thermodynamics. New York: McGraw-Hill, 1969.
6. J. Ågren, The Onsager Reciprocity Relations Revisited. J. Phase Equilib. Diffus. 2022, 43, p 640-647.10.1007/s11669-022-00951-y ↗
7. C. Becker, J. Ågren, M. Barrico, Q. Chen, S. Decterov, U. Kattner, J. Perepezko, G. Pottlacher, and M. Selleby, Thermodynamic Modelling of Liquids: Calphad Approaches and Contributions from Statistical Physics. Phys. Status Solidi B 2014, 251, p 33-52.10.1002/pssb.201350149 ↗
8. P. Benigni, Interest of the Regular 2-State Model for the Description of Unary Liquids: Presentation of the Formalism. Calphad 2023, 83, p 102627.10.1016/j.calphad.2023.102627 ↗
9. M. Cohen and D. Turnbull, Molecular Transport in Liquids and Glasses. J. Chem. Phys. 1959, 31, p 1164-1169.10.1063/1.1730566 ↗