journal article·2005-07-01

Adsorption of Alcohols from Aqueous Solutions into a Layered Silicate Modified with Octyltrichlorosilane

Ikuko Fujita, Kazuyuki Kuroda, Makoto Ogawa

Chemistry of Materials· Volume 17· Issue 14
Publisher page

Abstract

The adsorption of 1-hexanol and 1-butanol from water on the organically modified layered silicates, derived from magadiite by silylation with octyltrichlorosilane, was investigated. The degree of the interlamellar surface coverage of magadiite with octylsilyl groups affected the adsorptive properties. The modified magadiites with lower coverage adsorbed alcohols from aqueous solutions with lower concentrations. Both 1-hexanol and 1-butanol were adsorbed from aqueous solutions with very similar relative concentrations, suggesting that the solubilities of 1-hexanol and 1-butanol in water were correlated with the adsorption behavior. 1-Hexanol was adsorbed preferentially from a 1-hexanol/1-butanol aqueous mixture under limited conditions.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis · Adsorption and biosorption for pollutant removal

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Chemistry, Waseda University, Ohkubo 3-4-1, Shinjuku-ku, Tokyo 169-8555, Japan, Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, Nishiwaseda 2-8-26, Shinjuku-ku, Tokyo 169-0051, Japan, and Department of Earth Sciences, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo 169-8050, Japan

References (26)

Show source-provided references
1. Barrer R. M. · Clays Clay Miner. · 1989 · 37 · 38510.1346/CCMN.1989.0370501 ↗
2. Ogawa M. · Bull. Chem. Soc. Jpn. · 1997 · 70 · 259310.1246/bcsj.70.2593 ↗
3. Mortland M. M. · Clays Clay Miner. · 1986 · 34 · 58110.1346/CCMN.1986.0340512 ↗
4. Boyd S. A. · Nature · 1988 · 333 · 34510.1038/333345a0 ↗
5. Lee J. F. · J. Chem. Soc., Faraday Trans. 1 · 1989 · 85 · 295310.1039/f19898502953 ↗
6. Sheng G. · Clays Clay Miner. · 1998 · 46 · 1010.1346/CCMN.1998.0460102 ↗
7. Jaynes W. F. · Clays Clay Miner. · 1999 · 47 · 35810.1346/CCMN.1999.0470312 ↗
8. Marosi T. · Colloid Polym. Sci. · 1992 · 270 · 102710.1007/BF00655972 ↗
9. Marosi T. · Colloid Polym. Sci. · 1994 · 272 · 113610.1007/BF00652383 ↗
10. Regdon I. · Colloid Polym. Sci. · 1994 · 272 · 112910.1007/BF00652382 ↗
11. Dekany I. · Colloids Surf., A · 1996 · 119 · 710.1016/S0927-7757(96)03738-7 ↗
12. Johnson J. W. · J. Am. Chem. Soc. · 1989 · 111 · 38110.1021/ja00183a066 ↗
13. Johnson J. W. · Chem. Mater. · 1990 · 2 · 19810.1021/cm00008a024 ↗
14. Dékány I. · Colloid Polym. Sci. · 1997 · 275 · 68110.1007/s003960050135 ↗
15. Ogawa M. · J. Am. Chem. Soc. · 1998 · 120 · 736110.1021/ja981055s ↗
16. Ruiz-Hitzky E. · Nature · 1980 · 287 · 2810.1038/287028a0 ↗
17. Yanagisawa T. · React. Solids · 1988 · 5 · 16710.1016/0168-7336(88)80085-8 ↗
18. Okutomo S. · Appl. Clay Sci. · 1999 · 15 · 25310.1016/S0169-1317(99)00010-1 ↗
19. Ogawa M. · Chem. Mater. · 1998 · 10 · 378710.1021/cm980660r ↗
20. Yanagisawa T. · Bull. Chem. Soc. Jpn. · 1988 · 61 · 374310.1246/bcsj.61.3743 ↗
21. Isoda K. · Chem. Mater. · 2000 · 12 · 170210.1021/cm0000494 ↗
22. Ide Y. · Chem. Commun. · 2003 · 126210.1039/b301222k ↗
23. Ide Y. · Chem. Lett. · 2005 · 36010.1246/cl.2005.360 ↗
24. Eugster H. P. · Science · 1967 · 157 · 117710.1126/science.157.3793.1177 ↗
25. Fujita I. · Chem. Mater. · 2003 · 15 · 313410.1021/cm011698y ↗
26. Giles C. H. · J. Colloid Interface Sci. · 1974 · 47 · 3