Experimental Investigation of the Isothermal Section in Fe-Gd-Pd Ternary System at 873 K
Source abstract
Abstract
Isothermal section of Fe-Gd-Pd ternary system at 873 K has been established by means of x-ray diffraction (XRD), differential scanning calorimetry (DSC), and scanning electron microscope (SEM) with energy disperse x-ray spectroscopy (EDS) in backscattered electron imaging modes. The isothermal section consists of 14 single-phase regions, 25 two-phase regions, and 12 three-phase regions. At 873 K, no ternary compound was found and the binary inermetallic compounds Gd3Pd and Fe23Gd6 are not stable, whereas the compound Fe23Gd6 decomposes into compounds Fe17Gd2 and Fe3Gd. The XRD and the SEM/EDS analysis show that there is almost no solubility of Gd in the FePd and FePd3 phases, and the solubilities of Pd in Fe17Gd2, Fe3Gd and Fe2Gd and Fe in GdPd2, α-Gd3Pd4 and Gd3Pd2 are all less than 1 at.%. Meanwhile, the solubilities of Fe in GdPd3, α-GdPd and Gd7Pd3 are determined to be as high as 1.37, 5.31, and 4.18 at.% Fe, respectively.
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Research context
OpenAlex topics: Rare-earth and actinide compounds · Magnetic Properties of Alloys · Thermodynamic and Structural Properties of Metals and Alloys
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References (37)
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1. P. Chaudhari, J.J. Cuomo, and R.J. Gambino, Amorphous Metallic Films for Bubble Domain Applications, IBM J. Res. Dev., 1973, 17, p 66–6810.1147/rd.171.0066 ↗
2. Y. Mimura, N. Imamura, and T. Kobayashi, Preparation and Some Magnetic Properties of Amorphous Gd x Fe1−x Alloy Thin Films, Jpn. J. Appl. Phys., 1976, 47, p 368–37010.1063/1.322329 ↗
3. N. Imamura, Y. Mimura, and T. Kobayashi, Amorphous Gd-Fe Alloy Films Prepared by RF Cosputtering Technique, IEEE Trans. Magn., 1976, 12, p 55–6110.1109/TMAG.1976.1059009 ↗
4. N. Imamura, Y. Mimura, and T. Kobayashi, Magnetic Recording on GdFe Amorphous Alloy Films in Contact with Some Magnetic Materials, Jpn. J. Appl. Phys., 1976, 15, p 715–71610.1143/JJAP.15.715 ↗
5. K.J. Bryden and J.Y. Ying, Electrodeposition Synthesis and Hydrogen Absorption Properties of Nanostructured Palladium-Iron Alloys, Nanostruct. Mater., 1997, 9, p 485–48810.1016/S0965-9773(97)00106-2 ↗
6. P.V. Jasen, E.A. Gonzalez, N.J. Castellani, and A. Juan, Theoretical Study of Hydrogen Adsorption on FePd Face-Centered Cubic Alloy Surfaces, Phys. Rev. B, 2005, 71, p 23542210.1103/PhysRevB.71.235422 ↗
7. F.M. Takata, G. Pattanaik, W.A. Soffa, P.T.A. Sumodjo, and G. Zangari, Synthesis of L10 Fe-Pd Films by Electrodeposition and Thermal Annealing, Electrochem. Commun., 2008, 10, p 568–57110.1016/j.elecom.2008.01.041 ↗
8. Y. Ma, M. Zink, and S.G. Mayr, Biocompatibility of Single Crystalline fe70pd30 Ferromagnetic Shape Memory Films, Appl. Phys. Lett., 2010, 96, p 21370310.1063/1.3435260 ↗
9. D.T. CamThanh, E. Brück, O. Tegus, J.C.P. Klaasse, and K.H.J. Buschow, Influence of Si and Ge on the Magnetic Phase Transition and Magnetocaloric Properties of MnFe (P, Si, Ge), J. Magn. Magn. Mater., 2007, 310, p 1012–101410.1016/j.jmmm.2006.11.194 ↗
10. E. Brück, Topical Review: Developments in Magnetocaloric Refrigeration, J. Phys. D Appl. Phys., 2005, 38, p 381–39110.1088/0022-3727/38/23/R01 ↗
11. S.K. Tripany, K.G. Suresh, and A.K. Nigam, A Comparative Study of the Magnetocaloric Effect in Gd3Co and Gd3Ni, J. Magn. Magn. Mater., 2006, 306, p 24–2910.1016/j.jmmm.2006.02.253 ↗
12. B. Li, J. Du, W.J. Ren, W.J. Hu, Q. Zhang, D. Li, and Z.D. Zhang, Large Reversible Magnetocaloric Effect in Tb3Co Compound, Appl. Phys. Lett., 2008, 92, p 24250410.1063/1.2939220 ↗
13. F. Canepa, M. Napoletano, and S. Cirafici, Magnetocaloric Effect in the Intermetallic Compound Gd7Pd3, Intermetallics, 2002, 10, p 731–73410.1016/S0966-9795(02)00051-1 ↗
14. A.E. Dwight, The Unit-Cell Constants of Some PuNi3-Type Compounds, Acta Crystallogr., 1968, 24, p 1395–139610.1107/S056774086800436X ↗
15. A.S. Saleh, L.A. Saleh, N.M. Nayfeh, S.H. Mahmood, and I. Abu-Aljarayesh, Structural and Magnetic Studies of the Alloy System GdAg1−xFe x , J. Appl. Phys., 1992, 71, p 1893–189510.1063/1.351176 ↗
16. F. Givord and R. Lemaire, Structures Cristallines du Composé Intermétallique (Gd23Fe23)Fe5, J. Less Common Met., 1970, 21, p 463–46810.1016/0022-5088(70)90054-8 ↗
17. H. Nagai, N. Oyama, Y. Ikami, H. Yoshie, and A. Tsujimura, The Magnetic Properties of Pseudo-Binary Compounds, Gd(Fe1-xMn x )2 and Gd6(Fe1-yMn y )23, J. Phys. Soc. Jpn., 1986, 55, p 177–18310.1143/JPSJ.55.177 ↗
18. X.L. Chen, J. Wang, T.L. Chen, X.D. Li, M.H. Rong, G.H. Rao, and H.Y. Zhou, Thermodynamic Re-assessment of the Fe-Gd and Fe-Sm Binary Systems, Calphad, 2017, 58, p 151–15910.1016/j.calphad.2017.07.005 ↗
19. H. Okamoto, Phase Diagrams of Binary Iron Alloys, H. Okamoto, Ed., ASM International, Materials Park, 1993, p 341–349
20. J.H. Tian, J.K. Liang, S.S. Xie, C. Chen, and Y.Q. Wang, The Crystal Structure and the Room Temperature Section of Ternary Phase Diagram in the System Gd-Fe-Ti, Sci. China Ser. A, 1992, 35, p 1327–1335
21. S. Atiq, R.D. Rawlings, and D.R.F. West, Phase Relationships in the Fe-Co-Gd System, J. Mater. Sci. Lett., 1990, 9, p 518–51910.1007/BF00725862 ↗
22. K.H.J. Buschow, P.G. van Engen, and R. Jongebreur, Magneto-optical Properties of Metallic Ferromagnetic Materials, J. Magn. Magn. Mater., 1983, 38, p 1–2210.1016/0304-8853(83)90097-5 ↗
23. B.V. Cherkashin, Y.A. Vereshchagin, A.A. Kuranov, and F.A. Sidorenko, Atomic Ordering in Solid Solutions, Fiz. Met. Metalloved., 1983, 55, p 394–396
24. G. Borzone, G. Cacciamani, and R. Ferro, Systematics of Rare Earth-Palladium Alloys: Revision of a Few Systems and Forecast of the Tb-Pd Phase Diagram, Calphad, 1990, 14, p 139–14910.1016/0364-5916(90)90015-R ↗
25. T.B. Massalski, J.L. Murray, L.H. Bennett, and H. Baker, Binary Alloy Phase Diagrams, ASM, Materials Park, 1990, p 2
26. C. Colinet, A. Pasturel, and K.H.J. Buschow, Study of the Enthalpies of Formation in the Gd-(Fe Co, Pd, Pt) Systems, Metall. Mater. Trans. A, 1991, 18, p 903–90710.1007/BF02646931 ↗
27. K.H.J. Buschow and D.B. De Mooij, The Effect of H2 Absorption on the Magnetic Properties of Gd-Pd Intermetallic Compounds, Phys. Status Solidi, 2010, 84, p 207–21310.1002/pssa.2210840126 ↗
28. M.P.J. Punkkinen, K. Kokko, and I.J. Väyrynen, Electronic Structure of the Intermetallic Compound Gd3Pd, J. Alloys Compd., 2003, 34, p 5–810.1016/S0925-8388(02)00952-0 ↗
29. E. Talik, M. Neumann, and T. Mydlarz, Photoemission Study and Magnetization of Gd3Pd Intermetallic Compound, J. Magn. Magn. Mater., 1998, 189, p 183–18810.1016/S0304-8853(98)00245-5 ↗
30. E. Talik and A. Ślebarski, Properties of Gd3T Compounds (T = Rh, Ir, Pd), J. Alloys Compd., 1995, 223, p 87–9010.1016/0925-8388(94)01487-6 ↗
31. E.P. Yelsukov, E.V. Voronina, and V.A. Barinov, Mössbauer Study of Magnetic Properties Formation in Disordered Fe-Al Alloys, J. Magn. Magn. Mater., 1992, 115, p 271–28010.1016/0304-8853(92)90069-Z ↗
32. D.M. Sweger, R. Segnan, and J.J. Rhyne, Temperature Dependence of Hyperfine Interactions in Dy-Gd Alloys, Phys. Rev. B, 1974, 9, p 3864–387010.1103/PhysRevB.9.3864 ↗
33. Y. Sakamoto, F.L. Chen, and R.A. Mcnicholl, Thermodynamic Studies of Hydrogen Solution in Pd-Sc Alloys, J. Alloys Compd., 1993, 192, p 145–14810.1016/0925-8388(93)90213-7 ↗
34. Materials Data JADE Release 5, XRD Pattern Processing, Materials Data Inc. v (MDI), 1999
35. J.F. Smith and D.A. Hansen, The Structures of YNi3, YC03, ThFe3 and GdFe3, Acta Crystallogr., 2010, 19, p 1019–102410.1107/S0365110X65004814 ↗
36. N.F. Chaban, Y.B. Kuz’ma, N.S. Bilonizhko, O.O. Kachmar, and N.V. Petrov, Ternary (Nd, Sm, Gd)-Fe-B Systems, Dopov. Akad. Nauk URSR Ser A Fit. Mat. Tekh. Nauki., 1979, 10, p 873–876
37. X.L. Xu, Y.S. Du, G. Cheng, J.J. Huo, and L. Li, Phase Equilibria of the Gd-Fe-B Ternary System at 873 and 1073 K, J. Phase Equilib. Diffus., 2017, 38, p 576–58810.1007/s11669-017-0554-7 ↗